Aliquat A336® - a versatile and affordable cation source for an entirely new family of hydrophobic ionic liquids

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Sammanfattning

A novel family of ionic liquids based on the tricaprylmethylammonium cation [C25H54N+] combined with a number of anions that are easily and elegantly prepared by means of simple replacement of the chloride, [Cl], anion in Aliquat 336®—an ionic liquid itself—is introduced. Ionic liquids for engineering purposes should be affordable, easy to handle (i.e. air and moisture stable) and preferably simple to prepare by a non-expert in synthetic chemistry. Consequently, this paper introduces a viable option as a family of engineering-purpose ionic liquids derived from Aliquat 336®. Moreover, the prepared materials can be utilized, e.g. in heterogenized form as a catalyst incorporating catalytically active metal species (Pd) for the hydrogenation of an α,β-unsaturated aldehyde, citral.
OriginalspråkEngelska
Sidor (från-till)250-255
TidskriftGreen Chemistry
Volym8
StatusPublicerad - 15 feb 2006
MoE-publikationstypA1 Tidskriftsartikel-refererad

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