Abstrakti
The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.
Alkuperäiskieli | Ei tiedossa |
---|---|
Sivut | 125–131 |
Sivumäärä | 7 |
Julkaisu | Catalysis Letters |
Vuosikerta | 103 |
Numero | 1-2 |
DOI - pysyväislinkit | |
Tila | Julkaistu - 2005 |
OKM-julkaisutyyppi | A1 Julkaistu artikkeli, soviteltu |
Keywords
- carbon-supported palladium catalyst
- hydrogenolysis
- hydroxymatairesinol
- lignans
- matairesinol