Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

Heidi Markus; Päivi Mäki-Arvela; Narendra Kumar; Natalya V. Kul'kova; Patrik Christoffer Eklund; Rainer Sjöholm; Bjarne Holmbom; Tapio Salmi; Dmitry Murzin

doi:10.1007/s10562-005-6514-6

Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

Heidi Markus, Päivi Mäki-Arvela, Narendra Kumar, Natalya V. Kul'kova, Patrik Christoffer Eklund, Rainer Sjöholm, Bjarne Holmbom, Tapio Salmi, Dmitry Murzin

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

33 Citeringar (Scopus)

Sammanfattning

The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	125–131
Antal sidor	7
Tidskrift	Catalysis Letters
Volym	103
Nummer	1-2
DOI	https://doi.org/10.1007/s10562-005-6514-6
Status	Publicerad - 2005
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Nyckelord

carbon-supported palladium catalyst
hydrogenolysis
hydroxymatairesinol
lignans
matairesinol

Åtkomst av dokument

10.1007/s10562-005-6514-6

Citera det här

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title = "Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts",

abstract = "The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.",

keywords = "carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol, carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol, carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol",

author = "Heidi Markus and P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Kul'kova, {Natalya V.} and Eklund, {Patrik Christoffer} and Rainer Sj{\"o}holm and Bjarne Holmbom and Tapio Salmi and Dmitry Murzin",

year = "2005",

doi = "10.1007/s10562-005-6514-6",

language = "Odefinierat/ok{\"a}nt",

volume = "103",

pages = "125–131",

journal = "Catalysis Letters",

issn = "1011-372X",

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TY - JOUR

T1 - Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

AU - Markus, Heidi

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Kul'kova, Natalya V.

AU - Eklund, Patrik Christoffer

AU - Sjöholm, Rainer

AU - Holmbom, Bjarne

AU - Salmi, Tapio

AU - Murzin, Dmitry

PY - 2005

Y1 - 2005

N2 - The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

AB - The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

U2 - 10.1007/s10562-005-6514-6

DO - 10.1007/s10562-005-6514-6

M3 - Artikel

SN - 1011-372X

VL - 103

SP - 125

EP - 131

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -