Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

Heidi Markus; Päivi Mäki-Arvela; Narendra Kumar; Natalya V. Kul'kova; Patrik Christoffer Eklund; Rainer Sjöholm; Bjarne Holmbom; Tapio Salmi; Dmitry Murzin

doi:10.1007/s10562-005-6514-6

Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

Heidi Markus, Päivi Mäki-Arvela, Narendra Kumar, Natalya V. Kul'kova, Patrik Christoffer Eklund, Rainer Sjöholm, Bjarne Holmbom, Tapio Salmi, Dmitry Murzin

Research output: Contribution to journal › Article › Scientific › peer-review

33 Citations (Scopus)

Abstract

The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

Original language	Undefined/Unknown
Pages (from-to)	125–131
Number of pages	7
Journal	Catalysis Letters
Volume	103
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-005-6514-6
Publication status	Published - 2005
MoE publication type	A1 Journal article-refereed

Keywords

carbon-supported palladium catalyst
hydrogenolysis
hydroxymatairesinol
lignans
matairesinol

Access to Document

10.1007/s10562-005-6514-6

Cite this

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title = "Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts",

abstract = "The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.",

keywords = "carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol, carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol, carbon-supported palladium catalyst, hydrogenolysis, hydroxymatairesinol, lignans, matairesinol",

author = "Heidi Markus and P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Kul'kova, {Natalya V.} and Eklund, {Patrik Christoffer} and Rainer Sj{\"o}holm and Bjarne Holmbom and Tapio Salmi and Dmitry Murzin",

year = "2005",

doi = "10.1007/s10562-005-6514-6",

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volume = "103",

pages = "125–131",

journal = "Catalysis Letters",

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T1 - Hydrogenolysis of hydroxymatairesinol over carbon-supported palladium catalysts

AU - Markus, Heidi

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Kul'kova, Natalya V.

AU - Eklund, Patrik Christoffer

AU - Sjöholm, Rainer

AU - Holmbom, Bjarne

AU - Salmi, Tapio

AU - Murzin, Dmitry

PY - 2005

Y1 - 2005

N2 - The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

AB - The natural lignan hydroxymatairesinol was hydrogenolysed to a potential anticarcinogenic substance matairesinol over different carbon-supported palladium catalysts. The reaction was conducted in 2-propanol at 70 degrees C under hydrogen flow in a stirred glass reactor. The catalysts were characterised by N-2-physisorption, CO pulse chemisorption and pH measurement of aqueous catalyst slurries. The most active catalyst (Degussa-Huls) gave yields of matairesinol over 90% in 4 h. It was concluded that the acidity of the catalyst had a profound influence on the reaction rate.

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

KW - carbon-supported palladium catalyst

KW - hydrogenolysis

KW - hydroxymatairesinol

KW - lignans

KW - matairesinol

U2 - 10.1007/s10562-005-6514-6

DO - 10.1007/s10562-005-6514-6

M3 - Artikel

SN - 1011-372X

VL - 103

SP - 125

EP - 131

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -