57Fe Mössbauer spectroscopy investigation of La0.7Ca0.3Mn0.5Fe0.5O3

VS Zakhvalinskii; EA Piliuk; SV Taran; Anastasia Sklyarova; VV Matveev; Johan Linden; I. Zakharchuk

doi:10.1016/j.rinp.2016.11.032

⁵⁷Fe Mössbauer spectroscopy investigation of La_0.7Ca_0.3Mn_0.5Fe_0.5O₃

VS Zakhvalinskii, EA Piliuk, SV Taran, Anastasia Sklyarova, VV Matveev, Johan Linden, I. Zakharchuk

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

1 Sitaatiot (Scopus)

33 Lataukset (Pure)

Abstrakti

A La_0.7Ca_0.3Mn_0.5Fe_0.5O₃ (LCMFO) ceramic sample was produced using conventional solid-state reactions. According to the X-ray diffraction data, the obtained sample has an orthorhombic space group Pnma (a = 5.482(2) Å, b = 7.739(3) Å, c = 5.446(3) Å). Magnetic properties of the obtained sample were studied by ⁵⁷Fe Mössbauer spectroscopy in the temperature interval of 77–423 K. All spectra recorded at roomtemperature exhibit the presence of trivalent Fe. Mössbauer spectra of the LCMFO sample show the presence of two intensive components: a paramagnetic doublet and a magnetic sextet, and several weak magnetic sextets. Within the investigated temperature range, phase separation and coexistence of a paramagnetic matrix and a phase of nano-sized antiferromagnetic clusters both below and above T_N werefound.

Alkuperäiskieli	Ei tiedossa
Sivut	1175–1177
Julkaisu	Results in Physics
Vuosikerta	6
DOI - pysyväislinkit	https://doi.org/10.1016/j.rinp.2016.11.032
Tila	Julkaistu - 2016
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Keywords

Clusters
Fe-57 Mossbauer spectra
Perovskite manganites
Phase separation

Pääsy asiakirjaan

10.1016/j.rinp.2016.11.032

57 Fe _0.5_Moss_LCMFO.pdfLopullinen julkaistu versio, 405 KB

https://www.journals.elsevier.com/results-in-physics/

Viittausmuodot

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title = "57Fe M{\"o}ssbauer spectroscopy investigation of La0.7Ca0.3Mn0.5Fe0.5O3",

abstract = "A La0.7Ca0.3Mn0.5Fe0.5O3 (LCMFO) ceramic sample was produced using conventional solid-state reactions. According to the X-ray diffraction data, the obtained sample has an orthorhombic space group Pnma (a = 5.482(2) {\AA}, b = 7.739(3) {\AA}, c = 5.446(3) {\AA}). Magnetic properties of the obtained sample were studied by 57Fe M{\"o}ssbauer spectroscopy in the temperature interval of 77–423 K. All spectra recorded at roomtemperature exhibit the presence of trivalent Fe. M{\"o}ssbauer spectra of the LCMFO sample show the presence of two intensive components: a paramagnetic doublet and a magnetic sextet, and several weak magnetic sextets. Within the investigated temperature range, phase separation and coexistence of a paramagnetic matrix and a phase of nano-sized antiferromagnetic clusters both below and above TN werefound.",

keywords = "Clusters, Fe-57 Mossbauer spectra, Perovskite manganites, Phase separation, Clusters, Fe-57 Mossbauer spectra, Perovskite manganites, Phase separation, Clusters, Fe-57 Mossbauer spectra, Perovskite manganites, Phase separation",

author = "VS Zakhvalinskii and EA Piliuk and SV Taran and Anastasia Sklyarova and VV Matveev and Johan Linden and I. Zakharchuk",

note = "fys.",

year = "2016",

doi = "10.1016/j.rinp.2016.11.032",

language = "Odefinierat/ok{\"a}nt",

volume = "6",

pages = "1175–1177",

journal = "Results in Physics",

issn = "2211-3797",

publisher = "Elsevier",

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TY - JOUR

T1 - 57Fe Mössbauer spectroscopy investigation of La0.7Ca0.3Mn0.5Fe0.5O3

AU - Zakhvalinskii, VS

AU - Piliuk, EA

AU - Taran, SV

AU - Sklyarova, Anastasia

AU - Matveev, VV

AU - Linden, Johan

AU - Zakharchuk, I.

N1 - fys.

PY - 2016

Y1 - 2016

N2 - A La0.7Ca0.3Mn0.5Fe0.5O3 (LCMFO) ceramic sample was produced using conventional solid-state reactions. According to the X-ray diffraction data, the obtained sample has an orthorhombic space group Pnma (a = 5.482(2) Å, b = 7.739(3) Å, c = 5.446(3) Å). Magnetic properties of the obtained sample were studied by 57Fe Mössbauer spectroscopy in the temperature interval of 77–423 K. All spectra recorded at roomtemperature exhibit the presence of trivalent Fe. Mössbauer spectra of the LCMFO sample show the presence of two intensive components: a paramagnetic doublet and a magnetic sextet, and several weak magnetic sextets. Within the investigated temperature range, phase separation and coexistence of a paramagnetic matrix and a phase of nano-sized antiferromagnetic clusters both below and above TN werefound.

AB - A La0.7Ca0.3Mn0.5Fe0.5O3 (LCMFO) ceramic sample was produced using conventional solid-state reactions. According to the X-ray diffraction data, the obtained sample has an orthorhombic space group Pnma (a = 5.482(2) Å, b = 7.739(3) Å, c = 5.446(3) Å). Magnetic properties of the obtained sample were studied by 57Fe Mössbauer spectroscopy in the temperature interval of 77–423 K. All spectra recorded at roomtemperature exhibit the presence of trivalent Fe. Mössbauer spectra of the LCMFO sample show the presence of two intensive components: a paramagnetic doublet and a magnetic sextet, and several weak magnetic sextets. Within the investigated temperature range, phase separation and coexistence of a paramagnetic matrix and a phase of nano-sized antiferromagnetic clusters both below and above TN werefound.

KW - Clusters

KW - Fe-57 Mossbauer spectra

KW - Perovskite manganites

KW - Phase separation

KW - Clusters

KW - Fe-57 Mossbauer spectra

KW - Perovskite manganites

KW - Phase separation

KW - Clusters

KW - Fe-57 Mossbauer spectra

KW - Perovskite manganites

KW - Phase separation

U2 - 10.1016/j.rinp.2016.11.032

DO - 10.1016/j.rinp.2016.11.032

M3 - Artikel

SN - 2211-3797

VL - 6

SP - 1175

EP - 1177

JO - Results in Physics

JF - Results in Physics

ER -