Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Mykola Moroz; Fiseha Tesfaye; Pavlo Demchenko; Myroslava Prokhorenko; Bohdan Rudyk; Orest  Pereviznyk; Emanuela  Mastronardo; Daniel Lindberg; Oleksandr Reshetnyak; Leena Hupa

doi:10.1007/978-3-031-50244-6_23

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Mykola Moroz^*, Fiseha Tesfaye, Pavlo Demchenko, Myroslava Prokhorenko, Bohdan Rudyk, Orest Pereviznyk, Emanuela Mastronardo, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa

^*Corresponding author for this work

Laboratory of Molecular Science and Engineering

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

Abstract

The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga ₂S ₅–AgBr–Ag ₂S below 600 K were investigated by the modified electromotive force (EMF) method using the Ag ⁺ catalysts as small nucleation centers of equilibrium phases. Division of the GaS–Ga ₂S ₅–AgBr–Ag ₂S was carried out with the participation of the following compounds Ag ₂S, GaS, Ga ₂S ₃, AgBr, Ag ₉GaS ₆, AgGaS ₂, Ag ₃SBr, Ag ₃Ga ₂S ₄Br, and Ag ₂₇Ga ₂S ₁₂Br ₉. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−) IE | NE | SSE | R{Ag ⁺} | PE | IE (+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte (glassy Ag ₃GeS ₃Br), PE is the positive electrode, R{Ag ⁺} is the region of Ag ⁺ diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag ₃Ga ₂S ₄Br and Ag ₂₇Ga ₂S ₁₂Br.

Original language	English
Title of host publication	Energy Technology 2024: Carbon Dioxide Management and Other Technologies
Editors	Chukwunwike Iloeje, Shafiq Alam, Donna Post Guillen, Fiseha Tesfaye, Lei Zhang, Susanna A. Hockaday, Neale R. Neelameggham, Hong Peng, Nawshad Haque, Onuralp Yücel, Alafara Abdullahi Baba
Place of Publication	Swizerland
Publisher	Springer, Cham
Pages	257-268
Volume	1
Edition	1
ISBN (Electronic)	978-3-031-50244-6
ISBN (Print)	978-3-031-50244-6, 978-3-031-50244-6, 978-3-031-50244-6, 978-3-031-50244-6, N 978-3-031-50243-9
DOIs	https://doi.org/10.1007/978-3-031-50244-6_23
Publication status	Published - 2024
MoE publication type	A4 Article in a conference publication
Event	2024 TMS Annual Meeting & Exhibition: Energy Technologies and CO2 Management - Hyatt Regency Orlando, Orlando, United States Duration: 3 Mar 2024 → 7 Mar 2024 Conference number: 153 http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC

Publication series

Name	Minerals, Metals and Materials Series
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	2024 TMS Annual Meeting & Exhibition
Abbreviated title	TMS 2024
Country/Territory	United States
City	Orlando
Period	03/03/24 → 07/03/24
Internet address	http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC

Keywords

Photovoltaic compounds
Phase equilibria
Thermodynamic properties
EMF method
Gibbs energy

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/978-3-031-50244-6_23

M182942_1_Accepted author manuscript, 935 KB

https://link.springer.com/chapter/10.1007/978-3-031-50244-6_23Licence: All rights reserved
https://urn.fi/URN:NBN:fi-fe202502038711

Innovative e-waste recycling processes for greener and more efficient recoveries of critical metals and energy
Tesfaye, F. (Principal Investigator), Vainio, E. (Co-Principal Investigator), Hupa, L. (Co-Investigator) & Jylhävuori, N. (Co-Investigator)
01/01/22 → 31/12/23
Project: Foundation

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Moroz, M., Tesfaye, F., Demchenko, P., Prokhorenko, M., Rudyk, B., Pereviznyk, O., Mastronardo, E., Lindberg, D., Reshetnyak, O., & Hupa, L. (2024). Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. In C. Iloeje, S. Alam, D. P. Guillen, F. Tesfaye, L. Zhang, S. A. Hockaday, N. R. Neelameggham, H. Peng, N. Haque, O. Yücel, & A. A. Baba (Eds.), Energy Technology 2024: Carbon Dioxide Management and Other Technologies (1 ed., Vol. 1, pp. 257-268). (Minerals, Metals and Materials Series). Springer, Cham. https://doi.org/10.1007/978-3-031-50244-6_23

Moroz, Mykola ; Tesfaye, Fiseha ; Demchenko, Pavlo et al. / Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. Energy Technology 2024: Carbon Dioxide Management and Other Technologies. editor / Chukwunwike Iloeje ; Shafiq Alam ; Donna Post Guillen ; Fiseha Tesfaye ; Lei Zhang ; Susanna A. Hockaday ; Neale R. Neelameggham ; Hong Peng ; Nawshad Haque ; Onuralp Yücel ; Alafara Abdullahi Baba. Vol. 1 1. ed. Swizerland : Springer, Cham, 2024. pp. 257-268 (Minerals, Metals and Materials Series).

@inproceedings{0c5b13b6147e43cb812e4230998a8196,

title = "Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices",

abstract = "The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga 2S 5–AgBr–Ag 2S below 600 K were investigated by the modified electromotive force (EMF) method using the Ag + catalysts as small nucleation centers of equilibrium phases. Division of the GaS–Ga 2S 5–AgBr–Ag 2S was carried out with the participation of the following compounds Ag 2S, GaS, Ga 2S 3, AgBr, Ag 9GaS 6, AgGaS 2, Ag 3SBr, Ag 3Ga 2S 4Br, and Ag 27Ga 2S 12Br 9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−) IE | NE | SSE | R{Ag +} | PE | IE (+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte (glassy Ag 3GeS 3Br), PE is the positive electrode, R{Ag +} is the region of Ag + diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag 3Ga 2S 4Br and Ag 27Ga 2S 12Br.",

keywords = "Photovoltaic compounds, Phase equilibria, Thermodynamic properties, EMF method, Gibbs energy",

author = "Mykola Moroz and Fiseha Tesfaye and Pavlo Demchenko and Myroslava Prokhorenko and Bohdan Rudyk and Orest Pereviznyk and Emanuela Mastronardo and Daniel Lindberg and Oleksandr Reshetnyak and Leena Hupa",

year = "2024",

doi = "10.1007/978-3-031-50244-6_23",

language = "English",

isbn = "978-3-031-50244-6",

volume = "1",

series = "Minerals, Metals and Materials Series",

publisher = "Springer, Cham",

pages = "257--268",

editor = "Chukwunwike Iloeje and Shafiq Alam and Guillen, {Donna Post} and Fiseha Tesfaye and Lei Zhang and Hockaday, {Susanna A.} and Neelameggham, {Neale R.} and Hong Peng and Nawshad Haque and Onuralp Y{\"u}cel and Baba, {Alafara Abdullahi}",

booktitle = "Energy Technology 2024: Carbon Dioxide Management and Other Technologies",

edition = "1",

note = "2024 TMS Annual Meeting & Exhibition : Energy Technologies and CO2 Management, TMS 2024 ; Conference date: 03-03-2024 Through 07-03-2024",

url = "http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC",

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Moroz, M, Tesfaye, F, Demchenko, P, Prokhorenko, M, Rudyk, B, Pereviznyk, O, Mastronardo, E, Lindberg, D, Reshetnyak, O & Hupa, L 2024, Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. in C Iloeje, S Alam, DP Guillen, F Tesfaye, L Zhang, SA Hockaday, NR Neelameggham, H Peng, N Haque, O Yücel & AA Baba (eds), Energy Technology 2024: Carbon Dioxide Management and Other Technologies. 1 edn, vol. 1, Minerals, Metals and Materials Series, Springer, Cham, Swizerland, pp. 257-268, 2024 TMS Annual Meeting & Exhibition, Orlando, Florida, United States, 03/03/24. https://doi.org/10.1007/978-3-031-50244-6_23

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. / Moroz, Mykola; Tesfaye, Fiseha; Demchenko, Pavlo et al.
Energy Technology 2024: Carbon Dioxide Management and Other Technologies. ed. / Chukwunwike Iloeje; Shafiq Alam; Donna Post Guillen; Fiseha Tesfaye; Lei Zhang; Susanna A. Hockaday; Neale R. Neelameggham; Hong Peng; Nawshad Haque; Onuralp Yücel; Alafara Abdullahi Baba. Vol. 1 1. ed. Swizerland: Springer, Cham, 2024. p. 257-268 (Minerals, Metals and Materials Series).

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

TY - GEN

T1 - Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

AU - Moroz, Mykola

AU - Tesfaye, Fiseha

AU - Demchenko, Pavlo

AU - Prokhorenko, Myroslava

AU - Rudyk, Bohdan

AU - Pereviznyk, Orest

AU - Mastronardo, Emanuela

AU - Lindberg, Daniel

AU - Reshetnyak, Oleksandr

AU - Hupa, Leena

N1 - Conference code: 153

PY - 2024

Y1 - 2024

N2 - The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga 2S 5–AgBr–Ag 2S below 600 K were investigated by the modified electromotive force (EMF) method using the Ag + catalysts as small nucleation centers of equilibrium phases. Division of the GaS–Ga 2S 5–AgBr–Ag 2S was carried out with the participation of the following compounds Ag 2S, GaS, Ga 2S 3, AgBr, Ag 9GaS 6, AgGaS 2, Ag 3SBr, Ag 3Ga 2S 4Br, and Ag 27Ga 2S 12Br 9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−) IE | NE | SSE | R{Ag +} | PE | IE (+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte (glassy Ag 3GeS 3Br), PE is the positive electrode, R{Ag +} is the region of Ag + diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag 3Ga 2S 4Br and Ag 27Ga 2S 12Br.

AB - The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga 2S 5–AgBr–Ag 2S below 600 K were investigated by the modified electromotive force (EMF) method using the Ag + catalysts as small nucleation centers of equilibrium phases. Division of the GaS–Ga 2S 5–AgBr–Ag 2S was carried out with the participation of the following compounds Ag 2S, GaS, Ga 2S 3, AgBr, Ag 9GaS 6, AgGaS 2, Ag 3SBr, Ag 3Ga 2S 4Br, and Ag 27Ga 2S 12Br 9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−) IE | NE | SSE | R{Ag +} | PE | IE (+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte (glassy Ag 3GeS 3Br), PE is the positive electrode, R{Ag +} is the region of Ag + diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag 3Ga 2S 4Br and Ag 27Ga 2S 12Br.

KW - Photovoltaic compounds

KW - Phase equilibria

KW - Thermodynamic properties

KW - EMF method

KW - Gibbs energy

U2 - 10.1007/978-3-031-50244-6_23

DO - 10.1007/978-3-031-50244-6_23

M3 - Conference contribution

SN - 978-3-031-50244-6

SN - N 978-3-031-50243-9

VL - 1

T3 - Minerals, Metals and Materials Series

SP - 257

EP - 268

BT - Energy Technology 2024: Carbon Dioxide Management and Other Technologies

A2 - Iloeje, Chukwunwike

A2 - Alam, Shafiq

A2 - Guillen, Donna Post

A2 - Tesfaye, Fiseha

A2 - Zhang, Lei

A2 - Hockaday, Susanna A.

A2 - Neelameggham, Neale R.

A2 - Peng, Hong

A2 - Haque, Nawshad

A2 - Yücel, Onuralp

A2 - Baba, Alafara Abdullahi

PB - Springer, Cham

CY - Swizerland

T2 - 2024 TMS Annual Meeting & Exhibition

Y2 - 3 March 2024 through 7 March 2024

ER -

Moroz M, Tesfaye F, Demchenko P, Prokhorenko M, Rudyk B, Pereviznyk O et al. Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. In Iloeje C, Alam S, Guillen DP, Tesfaye F, Zhang L, Hockaday SA, Neelameggham NR, Peng H, Haque N, Yücel O, Baba AA, editors, Energy Technology 2024: Carbon Dioxide Management and Other Technologies. 1 ed. Vol. 1. Swizerland: Springer, Cham. 2024. p. 257-268. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-031-50244-6_23

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Abstract

Publication series

Conference

Keywords

UN SDGs

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Innovative e-waste recycling processes for greener and more efficient recoveries of critical metals and energy

Cite this