Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Mykola Moroz; Fiseha Tesfaye; Pavlo Demchenko; Myroslava Prokhorenko; Bohdan Rudyk; Orest  Pereviznyk; Emanuela  Mastronardo; Daniel Lindberg; Oleksandr Reshetnyak; Leena Hupa

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Mykola Moroz^*, Fiseha Tesfaye, Pavlo Demchenko, Myroslava Prokhorenko, Bohdan Rudyk, Orest Pereviznyk, Emanuela Mastronardo, Daniel Lindberg, Oleksandr Reshetnyak, Leena Hupa

^*Corresponding author for this work

Laboratory of Molecular Science and Engineering

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

Abstract

The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga2S5–AgBr–Ag2S (I) below 600 K were investigated by the modified electromotive force (EMF) method using the Ag+ catalysts as small nucleation centers of equilibrium phases. Division of the system in the part (I) was carried out with the participation of the following compounds Ag2S, GaS, Ga2S3, AgBr, Ag9GaS6, AgGaS2, Ag3SBr, Ag3Ga2S4Br, and Ag27Ga2S12Br9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−)IE|NE|SSЕ|R{Ag+}|PЕ|IE(+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte, PE is the positive electrode, R{Ag+} is the region of Ag+ diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag3Ga2S4Br and Ag27Ga2S12Br.

Original language	English
Title of host publication	Energy Technology 2024: Carbon Dioxide Management and Other Technologies
Editors	Chukwunwike Iloeje, Shafiq Alam, Donna Post Guillen, Fiseha Tesfaye, Lei Zhang, Susanna A. C. Hockaday , Neale R. Neelameggham, Hong Peng, Nawshad Haque, Onuralp Yücel, Alafara Abdullahi Baba
Place of Publication	Swizerland
Publisher	Springer, Cham
Pages	257-268
Volume	1
Edition	1
ISBN (Electronic)	978-3-031-50244-6
ISBN (Print)	N 978-3-031-50243-9
Publication status	Published - 2024
MoE publication type	A3 Part of a book or another research book
Event	2024 TMS Annual Meeting & Exhibition: Energy Technologies and CO2 Management - Hyatt Regency Orlando, Orlando, United States Duration: 3 Mar 2024 → 7 Mar 2024 Conference number: 153 http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC

Publication series

Name	The Minerals, Metals & Materials Series (MMMS)
Publisher	Springer, Cham
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	2024 TMS Annual Meeting & Exhibition
Abbreviated title	TMS 2024
Country/Territory	United States
City	Orlando
Period	03/03/24 → 07/03/24
Internet address	http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC

Keywords

Photovoltaic compounds
Phase equilibria
Thermodynamic properties
EMF method
Gibbs energy

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

https://link.springer.com/chapter/10.1007/978-3-031-50244-6_23Licence: All rights reserved

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Accepted author manuscript, 935 KB
Embargo ends: 02/02/25

Innovative e-waste recycling processes for greener and more efficient recoveries of critical metals and energy
Tesfaye, F., Vainio, E., Hupa, L. & Jylhävuori, N.
01/01/22 → 31/12/23
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Moroz, M., Tesfaye, F., Demchenko, P., Prokhorenko, M., Rudyk, B., Pereviznyk, O., Mastronardo, E., Lindberg, D., Reshetnyak, O., & Hupa, L. (2024). Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. In C. Iloeje, S. Alam, D. Post Guillen, F. Tesfaye, L. Zhang, S. A. C. Hockaday , N. R. Neelameggham, H. Peng, N. Haque, O. Yücel, & A. A. Baba (Eds.), Energy Technology 2024: Carbon Dioxide Management and Other Technologies (1 ed., Vol. 1, pp. 257-268). (The Minerals, Metals & Materials Series (MMMS)). Springer, Cham. https://link.springer.com/chapter/10.1007/978-3-031-50244-6_23

Moroz, Mykola ; Tesfaye, Fiseha ; Demchenko, Pavlo et al. / Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. Energy Technology 2024: Carbon Dioxide Management and Other Technologies. editor / Chukwunwike Iloeje ; Shafiq Alam ; Donna Post Guillen ; Fiseha Tesfaye ; Lei Zhang ; Susanna A. C. Hockaday ; Neale R. Neelameggham ; Hong Peng ; Nawshad Haque ; Onuralp Yücel ; Alafara Abdullahi Baba. Vol. 1 1. ed. Swizerland : Springer, Cham, 2024. pp. 257-268 (The Minerals, Metals & Materials Series (MMMS)).

@inbook{0c5b13b6147e43cb812e4230998a8196,

title = "Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices",

abstract = " The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga2S5–AgBr–Ag2S (I) below 600 K were investigated by the modified electromotive force (EMF) method using the Ag+ catalysts as small nucleation centers of equilibrium phases. Division of the system in the part (I) was carried out with the participation of the following compounds Ag2S, GaS, Ga2S3, AgBr, Ag9GaS6, AgGaS2, Ag3SBr, Ag3Ga2S4Br, and Ag27Ga2S12Br9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−)IE|NE|SSЕ|R{Ag+}|PЕ|IE(+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte, PE is the positive electrode, R{Ag+} is the region of Ag+ diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag3Ga2S4Br and Ag27Ga2S12Br.",

keywords = "Photovoltaic compounds, Phase equilibria, Thermodynamic properties, EMF method, Gibbs energy",

author = "Mykola Moroz and Fiseha Tesfaye and Pavlo Demchenko and Myroslava Prokhorenko and Bohdan Rudyk and Orest Pereviznyk and Emanuela Mastronardo and Daniel Lindberg and Oleksandr Reshetnyak and Leena Hupa",

year = "2024",

language = "English",

isbn = "N 978-3-031-50243-9",

volume = "1",

series = "The Minerals, Metals & Materials Series (MMMS)",

publisher = "Springer, Cham",

pages = "257--268",

editor = "Iloeje, {Chukwunwike } and Alam, {Shafiq } and {Post Guillen}, {Donna } and Tesfaye, {Fiseha } and Zhang, {Lei } and {Hockaday }, {Susanna A. C. } and Neelameggham, {Neale R. } and Peng, {Hong } and Haque, {Nawshad } and Y{\"u}cel, {Onuralp } and Baba, {Alafara Abdullahi }",

booktitle = "Energy Technology 2024: Carbon Dioxide Management and Other Technologies",

edition = "1",

note = "2024 TMS Annual Meeting & Exhibition : Energy Technologies and CO2 Management, TMS 2024 ; Conference date: 03-03-2024 Through 07-03-2024",

url = "http://www.programmaster.org/PM/PM.nsf/UpcomingSymposia/83D3B5E94BBDEEFD85258948006A965C?OpenDocument&ParentUNID=DC407D8D1045893585258687004B57DC",

}

Moroz, M, Tesfaye, F, Demchenko, P, Prokhorenko, M, Rudyk, B, Pereviznyk, O, Mastronardo, E, Lindberg, D, Reshetnyak, O & Hupa, L 2024, Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. in C Iloeje, S Alam, D Post Guillen, F Tesfaye, L Zhang, SAC Hockaday , NR Neelameggham, H Peng, N Haque, O Yücel & AA Baba (eds), Energy Technology 2024: Carbon Dioxide Management and Other Technologies. 1 edn, vol. 1, The Minerals, Metals & Materials Series (MMMS), Springer, Cham, Swizerland, pp. 257-268, 2024 TMS Annual Meeting & Exhibition, Orlando, Florida, United States, 03/03/24. <https://link.springer.com/chapter/10.1007/978-3-031-50244-6_23>

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. / Moroz, Mykola; Tesfaye, Fiseha; Demchenko, Pavlo et al.
Energy Technology 2024: Carbon Dioxide Management and Other Technologies. ed. / Chukwunwike Iloeje; Shafiq Alam; Donna Post Guillen; Fiseha Tesfaye; Lei Zhang; Susanna A. C. Hockaday ; Neale R. Neelameggham; Hong Peng; Nawshad Haque; Onuralp Yücel; Alafara Abdullahi Baba. Vol. 1 1. ed. Swizerland: Springer, Cham, 2024. p. 257-268 (The Minerals, Metals & Materials Series (MMMS)).

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

TY - CHAP

T1 - Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

AU - Moroz, Mykola

AU - Tesfaye, Fiseha

AU - Demchenko, Pavlo

AU - Prokhorenko, Myroslava

AU - Rudyk, Bohdan

AU - Pereviznyk, Orest

AU - Mastronardo, Emanuela

AU - Lindberg, Daniel

AU - Reshetnyak, Oleksandr

AU - Hupa, Leena

N1 - Conference code: 153

PY - 2024

Y1 - 2024

N2 - The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga2S5–AgBr–Ag2S (I) below 600 K were investigated by the modified electromotive force (EMF) method using the Ag+ catalysts as small nucleation centers of equilibrium phases. Division of the system in the part (I) was carried out with the participation of the following compounds Ag2S, GaS, Ga2S3, AgBr, Ag9GaS6, AgGaS2, Ag3SBr, Ag3Ga2S4Br, and Ag27Ga2S12Br9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−)IE|NE|SSЕ|R{Ag+}|PЕ|IE(+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte, PE is the positive electrode, R{Ag+} is the region of Ag+ diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag3Ga2S4Br and Ag27Ga2S12Br.

AB - The phase equilibria of the Ag–Ga–S–AgBr system in the part GaS–Ga2S5–AgBr–Ag2S (I) below 600 K were investigated by the modified electromotive force (EMF) method using the Ag+ catalysts as small nucleation centers of equilibrium phases. Division of the system in the part (I) was carried out with the participation of the following compounds Ag2S, GaS, Ga2S3, AgBr, Ag9GaS6, AgGaS2, Ag3SBr, Ag3Ga2S4Br, and Ag27Ga2S12Br9. Reactions were performed by applying electrochemical cells (ECs) with the structure: (−)IE|NE|SSЕ|R{Ag+}|PЕ|IE(+), where IE is the inert electrode (graphite powder), NE is the negative electrode (silver powder), SSE is the solid-state electrolyte, PE is the positive electrode, R{Ag+} is the region of Ag+ diffusion into PE. The measured EMF and temperature values of ECs were used to determine the standard thermodynamic functions of the compounds Ag3Ga2S4Br and Ag27Ga2S12Br.

KW - Photovoltaic compounds

KW - Phase equilibria

KW - Thermodynamic properties

KW - EMF method

KW - Gibbs energy

M3 - Chapter

SN - N 978-3-031-50243-9

VL - 1

T3 - The Minerals, Metals & Materials Series (MMMS)

SP - 257

EP - 268

BT - Energy Technology 2024: Carbon Dioxide Management and Other Technologies

A2 - Iloeje, Chukwunwike

A2 - Alam, Shafiq

A2 - Post Guillen, Donna

A2 - Tesfaye, Fiseha

A2 - Zhang, Lei

A2 - Hockaday , Susanna A. C.

A2 - Neelameggham, Neale R.

A2 - Peng, Hong

A2 - Haque, Nawshad

A2 - Yücel, Onuralp

A2 - Baba, Alafara Abdullahi

PB - Springer, Cham

CY - Swizerland

T2 - 2024 TMS Annual Meeting & Exhibition

Y2 - 3 March 2024 through 7 March 2024

ER -

Moroz M, Tesfaye F, Demchenko P, Prokhorenko M, Rudyk B, Pereviznyk O et al. Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices. In Iloeje C, Alam S, Post Guillen D, Tesfaye F, Zhang L, Hockaday SAC, Neelameggham NR, Peng H, Haque N, Yücel O, Baba AA, editors, Energy Technology 2024: Carbon Dioxide Management and Other Technologies. 1 ed. Vol. 1. Swizerland: Springer, Cham. 2024. p. 257-268. (The Minerals, Metals & Materials Series (MMMS)).

Phase Equilibria and Thermodynamic Properties of Selected Compounds in the Ag–Ga–S–AgBr System for Modern Application in Energy Conversion Devices

Abstract

Publication series

Conference

Keywords

UN SDGs

Access to Document

Embargoed Document

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Projects

Innovative e-waste recycling processes for greener and more efficient recoveries of critical metals and energy

Cite this