One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal

Päivi Mäki-Arvela; Narendra Kumar; David Kubička; Ali Nasir; Teemu Heikkilä; Vesa Pekka Lehto; Rainer Sjöholm; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/j.molcata.2005.06.023

One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal

Päivi Mäki-Arvela, Narendra Kumar, David Kubička, Ali Nasir, Teemu Heikkilä, Vesa Pekka Lehto, Rainer Sjöholm, Tapio Salmi, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

43 Citations (Scopus)

Abstract

Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir.

Original language	English
Pages (from-to)	72-81
Number of pages	10
Journal	Journal of Molecular Catalysis A: Chemical
Volume	240
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2005.06.023
Publication status	Published - 3 Oct 2005
MoE publication type	A1 Journal article-refereed

Keywords

Bifunctional catalyst
Citral
Menthol
Ni-H-MCM-41

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10.1016/j.molcata.2005.06.023

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Mäki-Arvela, P., Kumar, N., Kubička, D., Nasir, A., Heikkilä, T., Lehto, V. P., Sjöholm, R., Salmi, T., & Murzin, D. Y. (2005). One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal. Journal of Molecular Catalysis A: Chemical, 240(1-2), 72-81. https://doi.org/10.1016/j.molcata.2005.06.023

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title = "One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal",

abstract = "Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir.",

keywords = "Bifunctional catalyst, Citral, Menthol, Ni-H-MCM-41",

author = "P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and David Kubi{\v c}ka and Ali Nasir and Teemu Heikkil{\"a} and Lehto, {Vesa Pekka} and Rainer Sj{\"o}holm and Tapio Salmi and Murzin, {Dmitry Yu}",

year = "2005",

month = oct,

day = "3",

doi = "10.1016/j.molcata.2005.06.023",

language = "English",

volume = "240",

pages = "72--81",

journal = "Journal of Molecular Catalysis A: Chemical",

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Mäki-Arvela, P , Kumar, N, Kubička, D, Nasir, A, Heikkilä, T, Lehto, VP, Sjöholm, R, Salmi, T & Murzin, DY 2005, 'One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal', Journal of Molecular Catalysis A: Chemical, vol. 240, no. 1-2, pp. 72-81. https://doi.org/10.1016/j.molcata.2005.06.023

One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal. / Mäki-Arvela, Päivi ; Kumar, Narendra; Kubička, David et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 240, No. 1-2, 03.10.2005, p. 72-81.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts

T2 - Effect of catalyst support and metal

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Kubička, David

AU - Nasir, Ali

AU - Heikkilä, Teemu

AU - Lehto, Vesa Pekka

AU - Sjöholm, Rainer

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

PY - 2005/10/3

Y1 - 2005/10/3

N2 - Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir.

AB - Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir.

KW - Bifunctional catalyst

KW - Citral

KW - Menthol

KW - Ni-H-MCM-41

UR - http://www.scopus.com/inward/record.url?scp=24144438651&partnerID=8YFLogxK

U2 - 10.1016/j.molcata.2005.06.023

DO - 10.1016/j.molcata.2005.06.023

M3 - Article

AN - SCOPUS:24144438651

SN - 1381-1169

VL - 240

SP - 72

EP - 81

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal

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