One-pot citral transformation to menthol over bifunctional micro- and mesoporous metal modified catalysts: Effect of catalyst support and metal

Päivi Mäki-Arvela, Narendra Kumar, David Kubička, Ali Nasir, Teemu Heikkilä, Vesa Pekka Lehto, Rainer Sjöholm, Tapio Salmi, Dmitry Yu Murzin*

*Korresponderande författare för detta arbete

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

30 Citeringar (Scopus)

Sammanfattning

Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir.

OriginalspråkEngelska
Sidor (från-till)72-81
Antal sidor10
TidskriftJournal of Molecular Catalysis A: Chemical
Volym240
Utgåva1-2
DOI
StatusPublicerad - 3 okt 2005
MoE-publikationstypA1 Tidskriftsartikel-refererad

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