Abstract
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
Original language | Undefined/Unknown |
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Pages (from-to) | 1004–1006 |
Number of pages | 3 |
Journal | Inorganic Chemistry Communications |
Volume | 12 |
Issue number | 10 |
DOIs | |
Publication status | Published - 2009 |
MoE publication type | A1 Journal article-refereed |
Keywords
- Chiral ligands
- Molybdenum
- Oxo complexes
- Phenolate ligands