A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)

Manian RDRS; Reko Leino; O Wichmann; A Lehtonen

doi:10.1016/j.inoche.2009.08.005

A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)

Manian RDRS, Reko Leino, O Wichmann, A Lehtonen

Research output: Contribution to journal › Article › Scientific › peer-review

8 Citations (Scopus)

Abstract

A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

Original language	Undefined/Unknown
Pages (from-to)	1004–1006
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2009.08.005
Publication status	Published - 2009
MoE publication type	A1 Journal article-refereed

Keywords

Chiral ligands
Molybdenum
Oxo complexes
Phenolate ligands

Access to Document

10.1016/j.inoche.2009.08.005

Cite this

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title = "A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)",

abstract = "A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.",

keywords = "Chiral ligands, Molybdenum, Oxo complexes, Phenolate ligands, Chiral ligands, Molybdenum, Oxo complexes, Phenolate ligands, Chiral ligands, Molybdenum, Oxo complexes, Phenolate ligands",

author = "Manian RDRS and Reko Leino and O Wichmann and A Lehtonen",

year = "2009",

doi = "10.1016/j.inoche.2009.08.005",

language = "Odefinierat/ok{\"a}nt",

volume = "12",

pages = "1004–1006",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)

AU - RDRS, Manian

AU - Leino, Reko

AU - Wichmann, O

AU - Lehtonen, A

PY - 2009

Y1 - 2009

N2 - A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

AB - A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

KW - Chiral ligands

KW - Molybdenum

KW - Oxo complexes

KW - Phenolate ligands

KW - Chiral ligands

KW - Molybdenum

KW - Oxo complexes

KW - Phenolate ligands

KW - Chiral ligands

KW - Molybdenum

KW - Oxo complexes

KW - Phenolate ligands

U2 - 10.1016/j.inoche.2009.08.005

DO - 10.1016/j.inoche.2009.08.005

M3 - Artikel

SN - 1387-7003

VL - 12

SP - 1004

EP - 1006

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -