Sammanfattning
A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
Originalspråk | Odefinierat/okänt |
---|---|
Sidor (från-till) | 1004–1006 |
Antal sidor | 3 |
Tidskrift | Inorganic Chemistry Communications |
Volym | 12 |
Nummer | 10 |
DOI | |
Status | Publicerad - 2009 |
MoE-publikationstyp | A1 Tidskriftsartikel-refererad |
Nyckelord
- Chiral ligands
- Molybdenum
- Oxo complexes
- Phenolate ligands