Preparation and characterization of MCM-41 supported metallocene catalysts for olefin polymerization

Hanna Rahiala; Isabelle Beurroies; Tom Eklund; Kimmo Hakala; Regis Gougeon; Philippe Trens; Jarl B. Rosenholm

doi:10.1006/jcat.1999.2657

Preparation and characterization of MCM-41 supported metallocene catalysts for olefin polymerization

Hanna Rahiala, Isabelle Beurroies, Tom Eklund, Kimmo Hakala, Regis Gougeon, Philippe Trens, Jarl B. Rosenholm

Molekylärvetenskap och -teknik

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

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The effect of the structure and surface properties of support material on metallocene (zirconocene chloride) adsorption and catalyst activity in ethene polymerization was studied. Commercial Grace silica, mesoporous silicate, MCM-41, and aluminium-modified MCM-41 were used as supports. The highest amount of zirconocene dichloride was adsorbed on Al-modified MCM-41 (Si/Al = 32), providing the most reactive sites for attachment of the active component on the support surface. The 13C-CPMAS NMR studies proved that Cp2ZrCl2 is bound to the support surface. Also the highest activity in ethene polymerization was obtained using this support. © 1999 Academic Press.

Originalspråk	Engelska
Sidor (från-till)	14-23
Antal sidor	10
Tidskrift	Journal of Catalysis
Volym	188
Nummer	1
DOI	https://doi.org/10.1006/jcat.1999.2657
Status	Publicerad - 1999
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

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10.1006/jcat.1999.2657

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title = "Preparation and characterization of MCM-41 supported metallocene catalysts for olefin polymerization",

abstract = "The effect of the structure and surface properties of support material on metallocene (zirconocene chloride) adsorption and catalyst activity in ethene polymerization was studied. Commercial Grace silica, mesoporous silicate, MCM-41, and aluminium-modified MCM-41 were used as supports. The highest amount of zirconocene dichloride was adsorbed on Al-modified MCM-41 (Si/Al = 32), providing the most reactive sites for attachment of the active component on the support surface. The 13C-CPMAS NMR studies proved that Cp2ZrCl2 is bound to the support surface. Also the highest activity in ethene polymerization was obtained using this support. {\textcopyright} 1999 Academic Press.",

keywords = "Heterogeneous catalysis, MCM-41, Mesoporous silicate, Metallocene, Olefin polymerization",

author = "Hanna Rahiala and Isabelle Beurroies and Tom Eklund and Kimmo Hakala and Regis Gougeon and Philippe Trens and Rosenholm, {Jarl B.}",

year = "1999",

doi = "10.1006/jcat.1999.2657",

language = "English",

volume = "188",

pages = "14--23",

journal = "Journal of Catalysis",

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TY - JOUR

T1 - Preparation and characterization of MCM-41 supported metallocene catalysts for olefin polymerization

AU - Rahiala, Hanna

AU - Beurroies, Isabelle

AU - Eklund, Tom

AU - Hakala, Kimmo

AU - Gougeon, Regis

AU - Trens, Philippe

AU - Rosenholm, Jarl B.

PY - 1999

Y1 - 1999

N2 - The effect of the structure and surface properties of support material on metallocene (zirconocene chloride) adsorption and catalyst activity in ethene polymerization was studied. Commercial Grace silica, mesoporous silicate, MCM-41, and aluminium-modified MCM-41 were used as supports. The highest amount of zirconocene dichloride was adsorbed on Al-modified MCM-41 (Si/Al = 32), providing the most reactive sites for attachment of the active component on the support surface. The 13C-CPMAS NMR studies proved that Cp2ZrCl2 is bound to the support surface. Also the highest activity in ethene polymerization was obtained using this support. © 1999 Academic Press.

AB - The effect of the structure and surface properties of support material on metallocene (zirconocene chloride) adsorption and catalyst activity in ethene polymerization was studied. Commercial Grace silica, mesoporous silicate, MCM-41, and aluminium-modified MCM-41 were used as supports. The highest amount of zirconocene dichloride was adsorbed on Al-modified MCM-41 (Si/Al = 32), providing the most reactive sites for attachment of the active component on the support surface. The 13C-CPMAS NMR studies proved that Cp2ZrCl2 is bound to the support surface. Also the highest activity in ethene polymerization was obtained using this support. © 1999 Academic Press.

KW - Heterogeneous catalysis

KW - MCM-41

KW - Mesoporous silicate

KW - Metallocene

KW - Olefin polymerization

UR - https://www.mendeley.com/catalogue/2a8daee9-cd72-3129-a524-df02f3ba18de/

U2 - 10.1006/jcat.1999.2657

DO - 10.1006/jcat.1999.2657

M3 - Article

SN - 0021-9517

VL - 188

SP - 14

EP - 23

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 1

ER -

Preparation and characterization of MCM-41 supported metallocene catalysts for olefin polymerization

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