Sammanfattning
A set of graphitic carbon nitride samples was prepared using a straightforward experimental procedure without templates and any subsequent treatments. The materials were studied in-depth using a range of physical and chemical methods such as X-ray diffraction, FTIR spectroscopy, elemental analysis (CHN), nitrogen physisorption, SEM, XPS, TPD CO2. The resulting g-C3N4 was shown to be highly efficient in carboxymethylation of cinnamyl alcohol with dimethyl carbonate yielding up to ca. 82 % of the desired cinnamyl methyl carbonate. In the studied conditions, an increase in the surface N atomic content leads to an increase in selectivity towards the desired carbonate, while a higher surface O content was beneficial for side products. Metal-free graphitic carbon nitride was shown to be one of the most productive (ca. 2 mol/h kgcat) in the investigated reaction among studied heterogeneous catalysts.
Originalspråk | Engelska |
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Tidskrift | ChemPlusChem |
DOI | |
Status | E-pub före tryck - 23 nov. 2023 |
MoE-publikationstyp | A1 Tidskriftsartikel-refererad |