Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System

GV Olivieri; T Cogliano; RB Torres; R Turco; T Salmi; R Tesser; V Russo; M Di Serio; R Giudici

doi:10.1021/acs.iecr.3c01562

Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System

GV Olivieri, T Cogliano, RB Torres, R Turco, T Salmi, R Tesser, V Russo, M Di Serio, R Giudici

Industrial Chemistry and Reaction Engineering

Tutkimustuotos: Lehtiartikkeli › Artikkeli › Tieteellinen › vertaisarvioitu

1 Sitaatiot (Scopus)

6 Lataukset (Pure)

Abstrakti

The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weight ratio, and formic acid-to-soybean + water weight ratio. The experimental results revealed that the temperature and water-to-soybean oil ratio bring the most relevant influence on the partition coefficient. The results were interpreted with an empirical mathematical model and two thermodynamic models, UNIQUAC (Universal Quasichemical) and NRTL (Non-Random Two Liquid). This investigation has relevance for the epoxidation of vegetable oils via the Prilezhaev concept. The approach can also be extended to other carboxylic acids, too.

Alkuperäiskieli	Englanti
Sivut	13825-13836
Sivumäärä	12
Julkaisu	Industrial & Engineering Chemistry Research
Vuosikerta	62
Numero	35
DOI - pysyväislinkit	https://doi.org/10.1021/acs.iecr.3c01562
Tila	Julkaistu - 6 syysk. 2023
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1021/acs.iecr.3c01562

olivieri-et-al-2023-determination-of-the-mass-transfer-parameters-and-partition-coefficients-for-formic-acid-waterLopullinen julkaistu versio, 3,06 MBLisenssi: CC BY

https://urn.fi/URN:NBN:fi-fe202401294609

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Viittausmuodot

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author = "GV Olivieri and T Cogliano and RB Torres and R Turco and T Salmi and R Tesser and V Russo and {Di Serio}, M and R Giudici",

year = "2023",

month = sep,

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doi = "10.1021/acs.iecr.3c01562",

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AU - Olivieri, GV

AU - Cogliano, T

AU - Torres, RB

AU - Turco, R

AU - Salmi, T

AU - Tesser, R

AU - Russo, V

AU - Di Serio, M

AU - Giudici, R

PY - 2023/9/6

Y1 - 2023/9/6

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