TY - JOUR
T1 - Selective Hydrogenation of Pyridine and Derivatives of It on Bimetallic Catalysts
AU - Kustov, A. L.
AU - Dunaev, S. F.
AU - Salmi, T.
N1 - Funding Information:
This work was supported by the RF Ministry of Science and Higher Education, grant no. 075-15-2021-978.
Publisher Copyright:
© 2022, The Author(s).
PY - 2022/10
Y1 - 2022/10
N2 - Abstract: A study is performed of the catalytic properties of bimetallic nanoparticles based on palladium and a base metal (silver or copper) in the selective hydrogenation of pyridine and derivatives of it with the formation of piperidine and derivatives of it. It is established that the effect of increasing the activity of bimetallic nanoparticles is associated with the small size of particles (2–3 nm), relative to monometallic palladium catalyst. The conversion of pyridine reaches 99% with a piperidine selectivity of 99% under mild conditions (60°C, pressure H2 = 70 atm).
AB - Abstract: A study is performed of the catalytic properties of bimetallic nanoparticles based on palladium and a base metal (silver or copper) in the selective hydrogenation of pyridine and derivatives of it with the formation of piperidine and derivatives of it. It is established that the effect of increasing the activity of bimetallic nanoparticles is associated with the small size of particles (2–3 nm), relative to monometallic palladium catalyst. The conversion of pyridine reaches 99% with a piperidine selectivity of 99% under mild conditions (60°C, pressure H2 = 70 atm).
UR - http://www.scopus.com/inward/record.url?scp=85139435238&partnerID=8YFLogxK
U2 - 10.1134/S0036024422100132
DO - 10.1134/S0036024422100132
M3 - Article
AN - SCOPUS:85139435238
SN - 0036-0244
VL - 96
SP - 2129
EP - 2132
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
IS - 10
ER -