Pd/H-Beta catalysts: Characterization and reactivity in piperonyl alcohol selective oxidation

Olga P. Tkachenko; Leonid M. Kustov; Andrey L. Tarasov; Konstantin V. Klementiev; Narendra Kumar; Dmitry Yu. Murzin

doi:10.1016/j.apcata.2009.02.049

Pd/H-Beta catalysts: Characterization and reactivity in piperonyl alcohol selective oxidation

Olga P. Tkachenko, Leonid M. Kustov, Andrey L. Tarasov, Konstantin V. Klementiev, Narendra Kumar, Dmitry Yu. Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

12 Citations (Scopus)

Abstract

Pd/H-Beta catalysts with different silica-to-alumina ratio prepared by an impregnation method have been studied by XANES/EXAFS, IR, XRD and TEM. It was shown that palladium in calcined Pd/H-Beta samples exists as palladium oxide that can be easily reduced to Pd metal. The catalysts were tested in selective oxidation of piperonyl alcohol to piperonylaldehyde at 80 °C. The Pd/H-Beta zeolite catalysts with the lowest silica-to-alumina ratio possess the highest catalytic activity in benzylic alcohol oxidation reaction.

Original language	English
Pages (from-to)	144-150
Number of pages	7
Journal	Applied Catalysis A: General
Volume	359
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2009.02.049
Publication status	Published - 15 May 2009
MoE publication type	A1 Journal article-refereed

Keywords

IR
Pd/H-Beta zeolites
Piperonyl alcohol oxidation
TEM
XAS

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@article{0b9ac43081f343b2881f7fcbc115c57d,

title = "Pd/H-Beta catalysts: Characterization and reactivity in piperonyl alcohol selective oxidation",

abstract = "Pd/H-Beta catalysts with different silica-to-alumina ratio prepared by an impregnation method have been studied by XANES/EXAFS, IR, XRD and TEM. It was shown that palladium in calcined Pd/H-Beta samples exists as palladium oxide that can be easily reduced to Pd metal. The catalysts were tested in selective oxidation of piperonyl alcohol to piperonylaldehyde at 80 °C. The Pd/H-Beta zeolite catalysts with the lowest silica-to-alumina ratio possess the highest catalytic activity in benzylic alcohol oxidation reaction.",

keywords = "IR, Pd/H-Beta zeolites, Piperonyl alcohol oxidation, TEM, XAS",

author = "Tkachenko, {Olga P.} and Kustov, {Leonid M.} and Tarasov, {Andrey L.} and Klementiev, {Konstantin V.} and Narendra Kumar and Murzin, {Dmitry Yu.}",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2011) by the Academy of Finland. Financial support from European Union through the Sixth Framework Program is gratefully acknowledged. Authors thank HASYLAB (DESY, Germany) for X-ray beam time (project I-20060224 EC). Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",

year = "2009",

month = may,

day = "15",

doi = "10.1016/j.apcata.2009.02.049",

language = "English",

volume = "359",

pages = "144--150",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Pd/H-Beta catalysts

T2 - Characterization and reactivity in piperonyl alcohol selective oxidation

AU - Tkachenko, Olga P.

AU - Kustov, Leonid M.

AU - Tarasov, Andrey L.

AU - Klementiev, Konstantin V.

AU - Kumar, Narendra

AU - Murzin, Dmitry Yu.

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2011) by the Academy of Finland. Financial support from European Union through the Sixth Framework Program is gratefully acknowledged. Authors thank HASYLAB (DESY, Germany) for X-ray beam time (project I-20060224 EC). Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2009/5/15

Y1 - 2009/5/15

N2 - Pd/H-Beta catalysts with different silica-to-alumina ratio prepared by an impregnation method have been studied by XANES/EXAFS, IR, XRD and TEM. It was shown that palladium in calcined Pd/H-Beta samples exists as palladium oxide that can be easily reduced to Pd metal. The catalysts were tested in selective oxidation of piperonyl alcohol to piperonylaldehyde at 80 °C. The Pd/H-Beta zeolite catalysts with the lowest silica-to-alumina ratio possess the highest catalytic activity in benzylic alcohol oxidation reaction.

AB - Pd/H-Beta catalysts with different silica-to-alumina ratio prepared by an impregnation method have been studied by XANES/EXAFS, IR, XRD and TEM. It was shown that palladium in calcined Pd/H-Beta samples exists as palladium oxide that can be easily reduced to Pd metal. The catalysts were tested in selective oxidation of piperonyl alcohol to piperonylaldehyde at 80 °C. The Pd/H-Beta zeolite catalysts with the lowest silica-to-alumina ratio possess the highest catalytic activity in benzylic alcohol oxidation reaction.

KW - IR

KW - Pd/H-Beta zeolites

KW - Piperonyl alcohol oxidation

KW - TEM

KW - XAS

UR - http://www.scopus.com/inward/record.url?scp=64149116764&partnerID=8YFLogxK

U2 - 10.1016/j.apcata.2009.02.049

DO - 10.1016/j.apcata.2009.02.049

M3 - Article

AN - SCOPUS:64149116764

SN - 0926-860X

VL - 359

SP - 144

EP - 150

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

IS - 1-2

ER -

Pd/H-Beta catalysts: Characterization and reactivity in piperonyl alcohol selective oxidation

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Keywords

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