TY - JOUR
T1 - Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al2O3 catalyst
AU - Toukoniitty, Esa
AU - Mäki-Arvela, Päivi
AU - Wärnå, Johan
AU - Salmi, Tapio
N1 - Funding Information:
The authors are grateful to Mr. Markku Reunanen for his contribution to the GC–MS analyses and to Mr. Kari Eränen for the construction of the hydrogenation equipment. The financial support received from the Academy of Finland and the Graduate School in Chemical Engineering is gratefully acknowledged.
Copyright:
Copyright 2007 Elsevier B.V., All rights reserved.
PY - 2001/3/30
Y1 - 2001/3/30
N2 - A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.
AB - A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.
KW - 1-Phenyl-1,2-propanedione
KW - Enantioselective hydrogenation
KW - Pt/AlO catalyst
UR - http://www.scopus.com/inward/record.url?scp=0035970426&partnerID=8YFLogxK
U2 - 10.1016/S0920-5861(00)00638-6
DO - 10.1016/S0920-5861(00)00638-6
M3 - Conference article
AN - SCOPUS:0035970426
SN - 0920-5861
VL - 66
SP - 411
EP - 417
JO - Catalysis Today
JF - Catalysis Today
IS - 2-4
T2 - Catalysis in Multiphase Reactors
Y2 - 29 May 2000 through 29 May 2000
ER -