Isomerization of β-pinene oxide over Sn-modified zeolites

Päivi Mäki-Arvela; Narendra Kumar; Sara Faten Diáz; Atte Aho; Mikko Tenho; Jarno Salonen; Anne-Riikka Leino; Krisztian Kordás; Pekka Laukkanen; Johnny Dahl; Iliya Sinev; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/j.molcata.2012.09.028

Isomerization of β-pinene oxide over Sn-modified zeolites

Päivi Mäki-Arvela, Narendra Kumar, Sara Faten Diáz, Atte Aho, Mikko Tenho, Jarno Salonen, Anne-Riikka Leino, Krisztian Kordás, Pekka Laukkanen, Johnny Dahl, Iliya Sinev, Tapio Salmi, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

33 Citations (Scopus)

Abstract

Four different Sn modified zeolites, namely three Beta zeolites with varying SiO₂/Al₂O₃ ratio along with Sn-Y were synthesized, and characterized by XRD, TEM, SEM, pyridine adsorption desorption, nitrogen adsorption, XPS and EXAFS. Kinetics in β-pinene oxide isomerization into myrtanal was studied at 70°C in toluene as a solvent with different catalysts. The initial isomerization rate increases with increasing acidity. Complete conversion of β-pinene oxide was achieved with the three most acidic catalysts within 30 min, whereas only 72% conversion in 1440 min was obtained with the catalyst exhibiting the lowest acidity, Sn-Beta-300. The catalyst most selective to the formation of myrtanal was Sn-Beta-300 giving 64% selectivity at 72% conversion, which is related to low amounts of acid sites.

Original language	English
Pages (from-to)	228-237
Number of pages	10
Journal	Journal of Molecular Catalysis A: Chemical
Volume	366
DOIs	https://doi.org/10.1016/j.molcata.2012.09.028
Publication status	Published - Jan 2013
MoE publication type	A1 Journal article-refereed

Keywords

Isomerization
Terpene epoxide
Tin
Zeolite

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10.1016/j.molcata.2012.09.028

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title = "Isomerization of β-pinene oxide over Sn-modified zeolites",

abstract = "Four different Sn modified zeolites, namely three Beta zeolites with varying SiO2/Al2O3 ratio along with Sn-Y were synthesized, and characterized by XRD, TEM, SEM, pyridine adsorption desorption, nitrogen adsorption, XPS and EXAFS. Kinetics in β-pinene oxide isomerization into myrtanal was studied at 70°C in toluene as a solvent with different catalysts. The initial isomerization rate increases with increasing acidity. Complete conversion of β-pinene oxide was achieved with the three most acidic catalysts within 30 min, whereas only 72% conversion in 1440 min was obtained with the catalyst exhibiting the lowest acidity, Sn-Beta-300. The catalyst most selective to the formation of myrtanal was Sn-Beta-300 giving 64% selectivity at 72% conversion, which is related to low amounts of acid sites.",

keywords = "Isomerization, Terpene epoxide, Tin, Zeolite",

author = "P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Di{\'a}z, {Sara Faten} and Atte Aho and Mikko Tenho and Jarno Salonen and Anne-Riikka Leino and Krisztian Kord{\'a}s and Pekka Laukkanen and Johnny Dahl and Iliya Sinev and Tapio Salmi and Murzin, {Dmitry Yu}",

year = "2013",

month = jan,

doi = "10.1016/j.molcata.2012.09.028",

language = "English",

volume = "366",

pages = "228--237",

journal = "Journal of Molecular Catalysis A: Chemical",

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T1 - Isomerization of β-pinene oxide over Sn-modified zeolites

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Diáz, Sara Faten

AU - Aho, Atte

AU - Tenho, Mikko

AU - Salonen, Jarno

AU - Leino, Anne-Riikka

AU - Kordás, Krisztian

AU - Laukkanen, Pekka

AU - Dahl, Johnny

AU - Sinev, Iliya

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

PY - 2013/1

Y1 - 2013/1

N2 - Four different Sn modified zeolites, namely three Beta zeolites with varying SiO2/Al2O3 ratio along with Sn-Y were synthesized, and characterized by XRD, TEM, SEM, pyridine adsorption desorption, nitrogen adsorption, XPS and EXAFS. Kinetics in β-pinene oxide isomerization into myrtanal was studied at 70°C in toluene as a solvent with different catalysts. The initial isomerization rate increases with increasing acidity. Complete conversion of β-pinene oxide was achieved with the three most acidic catalysts within 30 min, whereas only 72% conversion in 1440 min was obtained with the catalyst exhibiting the lowest acidity, Sn-Beta-300. The catalyst most selective to the formation of myrtanal was Sn-Beta-300 giving 64% selectivity at 72% conversion, which is related to low amounts of acid sites.

AB - Four different Sn modified zeolites, namely three Beta zeolites with varying SiO2/Al2O3 ratio along with Sn-Y were synthesized, and characterized by XRD, TEM, SEM, pyridine adsorption desorption, nitrogen adsorption, XPS and EXAFS. Kinetics in β-pinene oxide isomerization into myrtanal was studied at 70°C in toluene as a solvent with different catalysts. The initial isomerization rate increases with increasing acidity. Complete conversion of β-pinene oxide was achieved with the three most acidic catalysts within 30 min, whereas only 72% conversion in 1440 min was obtained with the catalyst exhibiting the lowest acidity, Sn-Beta-300. The catalyst most selective to the formation of myrtanal was Sn-Beta-300 giving 64% selectivity at 72% conversion, which is related to low amounts of acid sites.

KW - Isomerization

KW - Terpene epoxide

KW - Tin

KW - Zeolite

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U2 - 10.1016/j.molcata.2012.09.028

DO - 10.1016/j.molcata.2012.09.028

M3 - Article

AN - SCOPUS:84870237767

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VL - 366

SP - 228

EP - 237

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

ER -

Isomerization of β-pinene oxide over Sn-modified zeolites

Abstract

Keywords

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