Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

Ewelina Leino; Narendra Kumar; Päivi Mäki-Arvela; Atte Aho; Krisztián Kordás; Anne Riikka Leino; Andrey Shchukarev; Dmitry Yu Murzin; Jyri Pekka Mikkola

doi:10.1016/j.matchemphys.2013.08.012

Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

Ewelina Leino, Narendra Kumar, Päivi Mäki-Arvela, Atte Aho, Krisztián Kordás, Anne Riikka Leino, Andrey Shchukarev, Dmitry Yu Murzin^*, Jyri Pekka Mikkola

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

19 Citations (Scopus)

Abstract

Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO ₂ properties was discussed. Moreover, the comparison of CeO ₂ samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO₂. Significant variations in physico-chemical properties of CeO₂ by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO ₂ catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO₂ using butylene oxide as a dehydrating agent. The dependence of CeO₂ properties on its catalytic activity is evaluated in detail.

Original language	English
Pages (from-to)	65-75
Number of pages	11
Journal	Materials Chemistry and Physics
Volume	143
Issue number	1
DOIs	https://doi.org/10.1016/j.matchemphys.2013.08.012
Publication status	Published - 16 Dec 2013
MoE publication type	A1 Journal article-refereed

Keywords

Inorganic compounds
Oxides
Photoelectron spectroscopy
Surface properties

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Leino, E., Kumar, N., Mäki-Arvela, P., Aho, A., Kordás, K., Leino, A. R., Shchukarev, A., Murzin, D. Y., & Mikkola, J. P. (2013). Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate. Materials Chemistry and Physics, 143(1), 65-75. https://doi.org/10.1016/j.matchemphys.2013.08.012

Leino, Ewelina ; Kumar, Narendra ; Mäki-Arvela, Päivi ; Aho, Atte ; Kordás, Krisztián ; Leino, Anne Riikka ; Shchukarev, Andrey ; Murzin, Dmitry Yu ; Mikkola, Jyri Pekka. / Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate. In: Materials Chemistry and Physics. 2013 ; Vol. 143, No. 1. pp. 65-75.

@article{b3189b20848c4579b5c92951162646d5,

title = "Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate",

abstract = "Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.",

keywords = "Inorganic compounds, Oxides, Photoelectron spectroscopy, Surface properties",

author = "Ewelina Leino and Narendra Kumar and P{\"a}ivi M{\"a}ki-Arvela and Atte Aho and Kriszti{\'a}n Kord{\'a}s and Leino, {Anne Riikka} and Andrey Shchukarev and Murzin, {Dmitry Yu} and Mikkola, {Jyri Pekka}",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre ({\AA}A-PCC) within the Finnish Centre of Excellence Programme appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Ume{\aa} University Technical Chemistry whereupon financial support from Bio4Energy programme , Kempe and Knut & Alice Wallenberg Foundations is acknowledged. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.",

year = "2013",

month = dec,

day = "16",

doi = "10.1016/j.matchemphys.2013.08.012",

language = "English",

volume = "143",

pages = "65--75",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier",

number = "1",

}

Leino, E, Kumar, N , Mäki-Arvela, P , Aho, A, Kordás, K, Leino, AR, Shchukarev, A, Murzin, DY & Mikkola, JP 2013, 'Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate', Materials Chemistry and Physics, vol. 143, no. 1, pp. 65-75. https://doi.org/10.1016/j.matchemphys.2013.08.012

Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate. / Leino, Ewelina; Kumar, Narendra ; Mäki-Arvela, Päivi ; Aho, Atte; Kordás, Krisztián; Leino, Anne Riikka; Shchukarev, Andrey; Murzin, Dmitry Yu ; Mikkola, Jyri Pekka.

In: Materials Chemistry and Physics, Vol. 143, No. 1, 16.12.2013, p. 65-75.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

AU - Leino, Ewelina

AU - Kumar, Narendra

AU - Mäki-Arvela, Päivi

AU - Aho, Atte

AU - Kordás, Krisztián

AU - Leino, Anne Riikka

AU - Shchukarev, Andrey

AU - Murzin, Dmitry Yu

AU - Mikkola, Jyri Pekka

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre (ÅA-PCC) within the Finnish Centre of Excellence Programme appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Umeå University Technical Chemistry whereupon financial support from Bio4Energy programme , Kempe and Knut & Alice Wallenberg Foundations is acknowledged. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.

PY - 2013/12/16

Y1 - 2013/12/16

N2 - Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.

AB - Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO 2 properties was discussed. Moreover, the comparison of CeO 2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO 2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.

KW - Inorganic compounds

KW - Oxides

KW - Photoelectron spectroscopy

KW - Surface properties

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U2 - 10.1016/j.matchemphys.2013.08.012

DO - 10.1016/j.matchemphys.2013.08.012

M3 - Article

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VL - 143

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EP - 75

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

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