TY - JOUR
T1 - Auto-gasification of a biofuel
AU - Järvinen, M. P.
AU - Zevenhoven, R.
AU - Vakkilainen, E. K.
N1 - Funding Information:
The National Technology Agency of Finland (Tekes), Andritz-Ahlstrom Corporation, the Academy of Finland (Project No. 53606) and Walter Ahlström Foundation are gratefully acknowledged for financing this work.
Copyright:
Copyright 2004 Elsevier Science B.V., Amsterdam. All rights reserved.
PY - 2002/12/1
Y1 - 2002/12/1
N2 - A novel mechanism for gasifying a char is described. For thermally large particles (i.e., Bi > 0.1) the temperature distribution is non-uniform. Because different temperature regimes exist in the particle, the stages of drying, devolatilization (or pyrolysis), and reaction of the char may overlap. At some point the particle's surface is fully devolatilized, while the particle's interior is still undergoing drying and devolatilization. As H2O and CO2 flow out from the particle they pass through the hot surface layers of char. If the temperature is high enough, the char may be gasified. Black liquor was used here as a sample fuel. It has desirable properties for such auto-gasification; thermally large particles, a high initial water-content and a very porous and highly reactive char. Detailed numerical simulations suggest that 30 to 40% of the char may be converted simultaneously with devolatilization by auto-gasification. The larger the particle and the higher the temperature, the larger is the fraction of char gasified. For coal and peat, a typical particle size is too small for this mechanism to play any role when fired in pulverized fuel or fluidized bed furnaces. For burning wooden logs, the particle size is large and the pyrolysis time is ≈10 min., so then auto-gasification might be important.
AB - A novel mechanism for gasifying a char is described. For thermally large particles (i.e., Bi > 0.1) the temperature distribution is non-uniform. Because different temperature regimes exist in the particle, the stages of drying, devolatilization (or pyrolysis), and reaction of the char may overlap. At some point the particle's surface is fully devolatilized, while the particle's interior is still undergoing drying and devolatilization. As H2O and CO2 flow out from the particle they pass through the hot surface layers of char. If the temperature is high enough, the char may be gasified. Black liquor was used here as a sample fuel. It has desirable properties for such auto-gasification; thermally large particles, a high initial water-content and a very porous and highly reactive char. Detailed numerical simulations suggest that 30 to 40% of the char may be converted simultaneously with devolatilization by auto-gasification. The larger the particle and the higher the temperature, the larger is the fraction of char gasified. For coal and peat, a typical particle size is too small for this mechanism to play any role when fired in pulverized fuel or fluidized bed furnaces. For burning wooden logs, the particle size is large and the pyrolysis time is ≈10 min., so then auto-gasification might be important.
UR - http://www.scopus.com/inward/record.url?scp=0242629817&partnerID=8YFLogxK
U2 - 10.1016/S0010-2180(02)00415-7
DO - 10.1016/S0010-2180(02)00415-7
M3 - Article
AN - SCOPUS:0242629817
SN - 0010-2180
VL - 131
SP - 357
EP - 370
JO - Combustion and Flame
JF - Combustion and Flame
IS - 4
ER -