A study on lowering the detection limit with solid-state lead-selective electrodes

Grzegorz Lisak; Tomasz Sokalski; Johan Bobacka; Leo Harju; Andrzej Lewenstam

doi:10.1016/j.talanta.2010.09.043

A study on lowering the detection limit with solid-state lead-selective electrodes

Grzegorz Lisak, Tomasz Sokalski, Johan Bobacka, Leo Harju, Andrzej Lewenstam

Laboratory of Molecular Science and Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

23 Citations (Scopus)

Abstract

The detection limit of a Pb2+ ion-selective electrode with a solid state (PbS/Ag2S) membrane was successfully lowered to the nanomolar range. The electrode was applied in direct potentiometric determination of Pb2+ in aqueous solutions. Hydrodynamics, redox reaction at the solid-state surface as well as time dependency were investigated and found as key factors affecting the low detection limit. By optimizing these parameters improving detection limit by ca. three orders of magnitude was achieved. (C) 2010 Elsevier B.V. All rights reserved.

Original language	Undefined/Unknown
Pages (from-to)	436–440
Number of pages	5
Journal	Talanta
Volume	83
DOIs	https://doi.org/10.1016/j.talanta.2010.09.043
Publication status	Published - 2010
MoE publication type	A1 Journal article-refereed

Keywords

Solid-state lead-selective electrode
Direct determination of lead
Low detection limit

Access to Document

10.1016/j.talanta.2010.09.043

Cite this

@article{aaf6daeb79b14313a6fdfb680dfc6836,

title = "A study on lowering the detection limit with solid-state lead-selective electrodes",

abstract = "The detection limit of a Pb2+ ion-selective electrode with a solid state (PbS/Ag2S) membrane was successfully lowered to the nanomolar range. The electrode was applied in direct potentiometric determination of Pb2+ in aqueous solutions. Hydrodynamics, redox reaction at the solid-state surface as well as time dependency were investigated and found as key factors affecting the low detection limit. By optimizing these parameters improving detection limit by ca. three orders of magnitude was achieved. (C) 2010 Elsevier B.V. All rights reserved.",

keywords = "Solid-state lead-selective electrode, Direct determination of lead, Low detection limit, Solid-state lead-selective electrode, Direct determination of lead, Low detection limit, Solid-state lead-selective electrode, Direct determination of lead, Low detection limit",

author = "Grzegorz Lisak and Tomasz Sokalski and Johan Bobacka and Leo Harju and Andrzej Lewenstam",

year = "2010",

doi = "10.1016/j.talanta.2010.09.043",

language = "Odefinierat/ok{\"a}nt",

volume = "83",

pages = "436–440",

journal = "Talanta",

issn = "0039-9140",

publisher = "Elsevier",

}

TY - JOUR

T1 - A study on lowering the detection limit with solid-state lead-selective electrodes

AU - Lisak, Grzegorz

AU - Sokalski, Tomasz

AU - Bobacka, Johan

AU - Harju, Leo

AU - Lewenstam, Andrzej

PY - 2010

Y1 - 2010

N2 - The detection limit of a Pb2+ ion-selective electrode with a solid state (PbS/Ag2S) membrane was successfully lowered to the nanomolar range. The electrode was applied in direct potentiometric determination of Pb2+ in aqueous solutions. Hydrodynamics, redox reaction at the solid-state surface as well as time dependency were investigated and found as key factors affecting the low detection limit. By optimizing these parameters improving detection limit by ca. three orders of magnitude was achieved. (C) 2010 Elsevier B.V. All rights reserved.

AB - The detection limit of a Pb2+ ion-selective electrode with a solid state (PbS/Ag2S) membrane was successfully lowered to the nanomolar range. The electrode was applied in direct potentiometric determination of Pb2+ in aqueous solutions. Hydrodynamics, redox reaction at the solid-state surface as well as time dependency were investigated and found as key factors affecting the low detection limit. By optimizing these parameters improving detection limit by ca. three orders of magnitude was achieved. (C) 2010 Elsevier B.V. All rights reserved.

KW - Solid-state lead-selective electrode

KW - Direct determination of lead

KW - Low detection limit

KW - Solid-state lead-selective electrode

KW - Direct determination of lead

KW - Low detection limit

KW - Solid-state lead-selective electrode

KW - Direct determination of lead

KW - Low detection limit

U2 - 10.1016/j.talanta.2010.09.043

DO - 10.1016/j.talanta.2010.09.043

M3 - Artikel

SN - 0039-9140

VL - 83

SP - 436

EP - 440

JO - Talanta

JF - Talanta

ER -