Valence-state mixing and separation in (formula presented)

J. Lindén, A. Kjekshus

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57 Citeringar (Scopus)

Sammanfattning

A mixed-valence state, formally denoted as (Formula presented) is observed in the 300 K Mössbauer spectra of the most reduced samples of (Formula presented) Upon cooling below the Verwey-type transition temperature (Formula presented) the component assigned to (Formula presented) separates into a high-spin (Formula presented) state and an (Formula presented) state with an unusually low internal field. The separation of the mixed-valence state at (Formula presented) is also confirmed by magnetic susceptibility measurements and differential scanning calorimetry. A model is proposed which accounts for the variation of the amount of the mixed-valence state with the oxygen content parameter w.

OriginalspråkEngelska
Sidor (från-till)15251-15260
Antal sidor10
TidskriftPhysical Review B - Condensed Matter and Materials Physics
Volym60
Utgåva22
DOI
StatusPublicerad - 1999
MoE-publikationstypA1 Tidskriftsartikel-refererad

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