Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

Heidi Maria Bernas; Yuliya S. Demidova; Atte Aho; Irina L. Simakova; Narendra Kumar; Yosra Laribi; Philippe Perrichon; Reko Leino; Dmitry Murzin

doi:10.1007/s10562-014-1474-3

Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

Heidi Maria Bernas, Yuliya S. Demidova, Atte Aho, Irina L. Simakova, Narendra Kumar, Yosra Laribi, Philippe Perrichon, Reko Leino, Dmitry Murzin

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Sammanfattning

The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	955–963
Tidskrift	Catalysis Letters
Volym	145
Nummer	3
DOI	https://doi.org/10.1007/s10562-014-1474-3
Status	Publicerad - 2015
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

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10.1007/s10562-014-1474-3

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title = "Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline",

abstract = "The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.",

author = "Bernas, {Heidi Maria} and Demidova, {Yuliya S.} and Atte Aho and Simakova, {Irina L.} and Narendra Kumar and Yosra Laribi and Philippe Perrichon and Reko Leino and Dmitry Murzin",

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TY - JOUR

T1 - Transformations of 1-(2-aminophenyl)propan-2-ol to 2-methylindoline

AU - Bernas, Heidi Maria

AU - Demidova, Yuliya S.

AU - Aho, Atte

AU - Simakova, Irina L.

AU - Kumar, Narendra

AU - Laribi, Yosra

AU - Perrichon, Philippe

AU - Leino, Reko

AU - Murzin, Dmitry

N1 - tk. iok

PY - 2015

Y1 - 2015

N2 - The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

AB - The transformation reaction of 1-(2-aminophenyl)propan-2-ol was studied at 200°C under argon pressure. A range of catalysts was applied including carbon, titania and zeolite supported Ru, Pd, Pt, Rh, and Ir, as well as metal free zeolites. The highest conversion was obtained with H-Beta-150 and H-Beta-25 and the highest selectivity to 2-methylindoline was achieved with 0.3 % Ir–H-Beta-150 and H-Beta-25. Although the selectivity to 2-methylindole was high for all catalysts, formation of the final product 2-methylindoline only took place over the most acidic catalysts.

U2 - 10.1007/s10562-014-1474-3

DO - 10.1007/s10562-014-1474-3

M3 - Artikel

SN - 1011-372X

VL - 145

SP - 955

EP - 963

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3

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