The selective sorption of solvents on sulphonic acid polymer catalyst in binary mixtures

Johanna Lilja, Elena Murzina, Henrik Grénman, Hanna Vainio, Tapio Salmi, Dmitry Murzin

    Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

    6 Citeringar (Scopus)

    Sammanfattning

    The sorption behaviour of a polymer-supported sulphonic acid catalyst, Smopex-101, was studied in different solvent mixtures at 60 and 70 degrees C. The physical characteristics of the catalyst were investigated. Six catalysts with activities, ranging from 2.1 to 3.6 mmol/g, various degrees of cross-linking, 0%, 0.5%, 2% and 4% divinylbenzene as well as dimensions (lengths and diameters) were studied. The analyses of the liquid phase were carried out by using a densitometer. Catalyst swelling was studied with pure solvents as well as in acetic acid-ethyl acetate mixtures. The sorption phenomenon was found to be a complex one depending on the catalyst swelling.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)111–118
    Antal sidor8
    TidskriftReactive and Functional Polymers
    Volym64
    Utgåva2
    DOI
    StatusPublicerad - 2005
    MoE-publikationstypA1 Tidskriftsartikel-refererad

    Nyckelord

    • fibre catalyst
    • swelling

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