The Effect of Deposit Temperature on the Catalytic SO₂-to-SO₃ Conversion in a Copper Flash Smelting Heat Recovery Boiler

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The aim of the work was to study the catalytic role of copper flash smelter deposit in the SO2-to-SO3 conversion. In addition, the effect of process gas temperature at 548 K to 1173 K (275 °C to 900 °C) on the amount of SO3 formed was addressed both in the absence and presence of genuine copper flash smelter deposit. The SO3 conversion rate changed as a function of process gas temperature, peaking at 1023 K (750 °C). A dramatic increase in the SO2-to-SO3 conversion was observed when process dust was present, clearly indicating that process dust catalyzes the SO2-to-SO3 conversion. Based on these results, the catalytic ability of the deposit may lead to sulfuric acid dew point corrosion.

Sidor (från-till)434–439
TidskriftMetallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
StatusPublicerad - 2018
MoE-publikationstypA1 Tidskriftsartikel-refererad

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