Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

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Sammanfattning

Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.
OriginalspråkOdefinierat/okänt
Sidor (från-till)2557–2560
TidskriftSynlett
Volym27
Utgåva18
DOI
StatusPublicerad - 2016
MoE-publikationstypA1 Tidskriftsartikel-refererad

Nyckelord

  • chiral phosphites
  • chiral phosphates
  • conidendrin
  • Lignan
  • matairesinol
  • chiral pool
  • chiral 1,4-diols

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