Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene

Alexey A. Sadovnikov; Olga V. Arapova; Vincenzo Russo; Anton L. Maximov; Dmitry Yu Murzin

doi:10.1021/acs.iecr.1c04169

Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene

Alexey A. Sadovnikov
, Olga V. Arapova
, Vincenzo Russo
, Anton L. Maximov
, Dmitry Yu Murzin

Teknisk kemi och reaktionsteknik

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

19 Citeringar (Scopus)

Sammanfattning

Tuning the morphology of heterogeneous catalysts is of paramount importance for the design of efficient processes and requires detailed information on the physicochemical characteristics of the materials. Four micro-/mesoporous composites with different morphologies were synthesized by a dual-templating method using two-step crystallization with different zeolite seed concentrations. This work demonstrates the dependence of selectivity on the catalyst nature in solid-acid alkylation. It was demonstrated that a high concentration of weak acid sites leads to dialkyltoluene products, whereas a high concentration of strong acid sites is beneficial for other side reactions. It was shown that the morphology of catalysts played a crucial role in solid-acid alkylation. The alkylation mechanism defined in this study with different contributions of weak and strong acid sites could provide a route to the development of effective solid-acid catalysts.

Originalspråk	Engelska
Sidor (från-till)	1994-2009
Antal sidor	16
Tidskrift	Industrial and Engineering Chemistry Research
Volym	61
Nummer	5
DOI	https://doi.org/10.1021/acs.iecr.1c04169
Status	Publicerad - 9 feb. 2022
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Finansiering

This work was done as part of the TIPS RAS State Plan. The authors thank A.V. Shubnikov, Institute of Crystallography, RAS, for TEM analysis, Institute of macromolecular compounds, RAS, for NMR spectroscopy, and Dr. A.P. Glotov for his help with low-temperature adsorption-desorption of N2 measurements. The SEM analysis was performed using the equipment of the JRC PMR IGIC RAS.

Åtkomst av dokument

10.1021/acs.iecr.1c04169

Andra filer och länkar

Länk till publikationen i Scopus

Citera det här

@article{ec1e01dbc95a45eaa999e9d0f1d3abc9,

title = "Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene",

abstract = "Tuning the morphology of heterogeneous catalysts is of paramount importance for the design of efficient processes and requires detailed information on the physicochemical characteristics of the materials. Four micro-/mesoporous composites with different morphologies were synthesized by a dual-templating method using two-step crystallization with different zeolite seed concentrations. This work demonstrates the dependence of selectivity on the catalyst nature in solid-acid alkylation. It was demonstrated that a high concentration of weak acid sites leads to dialkyltoluene products, whereas a high concentration of strong acid sites is beneficial for other side reactions. It was shown that the morphology of catalysts played a crucial role in solid-acid alkylation. The alkylation mechanism defined in this study with different contributions of weak and strong acid sites could provide a route to the development of effective solid-acid catalysts.",

author = "Sadovnikov, \{Alexey A.\} and Arapova, \{Olga V.\} and Vincenzo Russo and Maximov, \{Anton L.\} and Murzin, \{Dmitry Yu\}",

note = "Funding Information: This work was done as part of the TIPS RAS State Plan. The authors thank A.V. Shubnikov, Institute of Crystallography, RAS, for TEM analysis, Institute of macromolecular compounds, RAS, for NMR spectroscopy, and Dr. A.P. Glotov for his help with low-temperature adsorption-desorption of N2 measurements. The SEM analysis was performed using the equipment of the JRC PMR IGIC RAS. Publisher Copyright: {\textcopyright} 2022 American Chemical Society",

year = "2022",

month = feb,

day = "9",

doi = "10.1021/acs.iecr.1c04169",

language = "English",

volume = "61",

pages = "1994--2009",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American chemical society",

number = "5",

}

TY - JOUR

T1 - Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene

AU - Sadovnikov, Alexey A.

AU - Arapova, Olga V.

AU - Russo, Vincenzo

AU - Maximov, Anton L.

AU - Murzin, Dmitry Yu

N1 - Funding Information: This work was done as part of the TIPS RAS State Plan. The authors thank A.V. Shubnikov, Institute of Crystallography, RAS, for TEM analysis, Institute of macromolecular compounds, RAS, for NMR spectroscopy, and Dr. A.P. Glotov for his help with low-temperature adsorption-desorption of N2 measurements. The SEM analysis was performed using the equipment of the JRC PMR IGIC RAS. Publisher Copyright: © 2022 American Chemical Society

PY - 2022/2/9

Y1 - 2022/2/9

N2 - Tuning the morphology of heterogeneous catalysts is of paramount importance for the design of efficient processes and requires detailed information on the physicochemical characteristics of the materials. Four micro-/mesoporous composites with different morphologies were synthesized by a dual-templating method using two-step crystallization with different zeolite seed concentrations. This work demonstrates the dependence of selectivity on the catalyst nature in solid-acid alkylation. It was demonstrated that a high concentration of weak acid sites leads to dialkyltoluene products, whereas a high concentration of strong acid sites is beneficial for other side reactions. It was shown that the morphology of catalysts played a crucial role in solid-acid alkylation. The alkylation mechanism defined in this study with different contributions of weak and strong acid sites could provide a route to the development of effective solid-acid catalysts.

AB - Tuning the morphology of heterogeneous catalysts is of paramount importance for the design of efficient processes and requires detailed information on the physicochemical characteristics of the materials. Four micro-/mesoporous composites with different morphologies were synthesized by a dual-templating method using two-step crystallization with different zeolite seed concentrations. This work demonstrates the dependence of selectivity on the catalyst nature in solid-acid alkylation. It was demonstrated that a high concentration of weak acid sites leads to dialkyltoluene products, whereas a high concentration of strong acid sites is beneficial for other side reactions. It was shown that the morphology of catalysts played a crucial role in solid-acid alkylation. The alkylation mechanism defined in this study with different contributions of weak and strong acid sites could provide a route to the development of effective solid-acid catalysts.

UR - https://www.scopus.com/pages/publications/85124160872

U2 - 10.1021/acs.iecr.1c04169

DO - 10.1021/acs.iecr.1c04169

M3 - Article

AN - SCOPUS:85124160872

SN - 0888-5885

VL - 61

SP - 1994

EP - 2009

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 5

ER -

Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene

Sammanfattning

Finansiering

Åtkomst av dokument

Andra filer och länkar

Fingeravtryck

Citera det här