Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

Marek Kosmulski; Piotr Próchniak; Jarl B. Rosenholm

doi:10.1021/la902659w

Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

Marek Kosmulski, Piotr Próchniak, Jarl B. Rosenholm

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

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The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

Originalspråk	Engelska
Sidor (från-till)	1904-1909
Antal sidor	6
Tidskrift	Langmuir
Volym	26
Nummer	3
DOI	https://doi.org/10.1021/la902659w
Status	Publicerad - feb. 2010
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

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title = "Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents",

abstract = "The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. {\textcopyright} 2009 American Chemical Society.",

author = "Marek Kosmulski and Piotr Pr{\'o}chniak and Rosenholm, {Jarl B.}",

year = "2010",

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AU - Kosmulski, Marek

AU - Próchniak, Piotr

AU - Rosenholm, Jarl B.

PY - 2010/2

Y1 - 2010/2

N2 - The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

AB - The presence of titania powder (chiefly anatase) enhanced electrolytic dissociation of oxalic acid in lower aliphatic alcohols (but not in water). The surface-induced dissociation was manifested in enhanced electric conductance of a dispersion containing solvent, oxalic acid, and titania, which was substantially higher than the conductance of dispersion containing only solvent and titania and of solution of oxalic acid in that solvent. This phenomenon can be applied to control the electrokinetic potential of particles in polar organic solvents. © 2009 American Chemical Society.

UR - https://www.mendeley.com/catalogue/079f87bf-af44-3f57-8db0-9f73aaf45011/

U2 - 10.1021/la902659w

DO - 10.1021/la902659w

M3 - Article

SN - 0743-7463

VL - 26

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JO - Langmuir

JF - Langmuir

IS - 3

ER -

Surface-induced electrolytic dissociation of oxalic acid in polar organic solvents

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