Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

Päivi Mäki-Arvela; Narendra Kumar; Ivo Paseka; Tapio Salmi; Dmitry Yu Murzin

doi:10.1007/s10562-004-8677-y

Support effects in nerol hydrogenation over Pt/SiO₂, Pt/H-Y and Pt/H-MCM-41 catalysts

Päivi Mäki-Arvela
, Narendra Kumar
, Ivo Paseka
, Tapio Salmi
, Dmitry Yu Murzin^*

^*Korresponderande författare för detta arbete

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

9 Citeringar (Scopus)

Sammanfattning

Chemoselective hydrogenation of nerol was investigated over Pt/SiO ₂, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO₂ > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO₂, Pt/H-MCM-41 and Pt/H-Y, respectively.

Originalspråk	Engelska
Sidor (från-till)	173-179
Antal sidor	7
Tidskrift	Catalysis Letters
Volym	98
Nummer	4
DOI	https://doi.org/10.1007/s10562-004-8677-y
Status	Publicerad - dec. 2004
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Finansiering

This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Authors are grateful to Mr. Markku Reunanen (Åba Akademi) for the MS analysis and to Mr. Teemu Heikkilä, University of Turku for XRD measurements.

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10.1007/s10562-004-8677-y

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@article{fdca413172c642179ced8a893a421879,

title = "Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts",

abstract = "Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30\% conversion of nerol were 65\%, 55\% and 25\% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.",

keywords = "H-MCM-41, Hydrogenation, Kinetics, Nerol, Pt, Selectivity",

author = "P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Ivo Paseka and Tapio Salmi and Murzin, \{Dmitry Yu\}",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Authors are grateful to Mr. Markku Reunanen ({\AA}ba Akademi) for the MS analysis and to Mr. Teemu Heikkil{\"a}, University of Turku for XRD measurements. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2004",

month = dec,

doi = "10.1007/s10562-004-8677-y",

language = "English",

volume = "98",

pages = "173--179",

journal = "Catalysis Letters",

issn = "1011-372X",

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number = "4",

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TY - JOUR

T1 - Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Paseka, Ivo

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Authors are grateful to Mr. Markku Reunanen (Åba Akademi) for the MS analysis and to Mr. Teemu Heikkilä, University of Turku for XRD measurements. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2004/12

Y1 - 2004/12

N2 - Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.

AB - Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.

KW - H-MCM-41

KW - Hydrogenation

KW - Kinetics

KW - Nerol

KW - Pt

KW - Selectivity

UR - https://www.scopus.com/pages/publications/10444286684

U2 - 10.1007/s10562-004-8677-y

DO - 10.1007/s10562-004-8677-y

M3 - Article

AN - SCOPUS:10444286684

SN - 1011-372X

VL - 98

SP - 173

EP - 179

JO - Catalysis Letters

JF - Catalysis Letters

IS - 4

ER -