Preparation of chiral indenes containing β-pinenyl derived ligand substituents

S Silver; E Johansson; R Sjoholm; Reko Leino

doi:10.1016/j.tetlet.2003.10.186

Preparation of chiral indenes containing β-pinenyl derived ligand substituents

S Silver, E Johansson, R Sjoholm, Reko Leino

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

2 Citeringar (Scopus)

Sammanfattning

A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	249–252
Antal sidor	4
Tidskrift	Tetrahedron Letters
Volym	45
Nummer	2
DOI	https://doi.org/10.1016/j.tetlet.2003.10.186
Status	Publicerad - 2004
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Nyckelord

chirality
indene
indenyl
metallocenes

Åtkomst av dokument

10.1016/j.tetlet.2003.10.186

Citera det här

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title = "Preparation of chiral indenes containing β-pinenyl derived ligand substituents",

abstract = "A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.",

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author = "S Silver and E Johansson and R Sjoholm and Reko Leino",

year = "2004",

doi = "10.1016/j.tetlet.2003.10.186",

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T1 - Preparation of chiral indenes containing β-pinenyl derived ligand substituents

AU - Silver, S

AU - Johansson, E

AU - Sjoholm, R

AU - Leino, Reko

PY - 2004

Y1 - 2004

N2 - A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

AB - A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

U2 - 10.1016/j.tetlet.2003.10.186

DO - 10.1016/j.tetlet.2003.10.186

M3 - Artikel

SN - 0040-4039

VL - 45

SP - 249

EP - 252

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -