Phase distribution of resin and fatty acids in colloidal wood pitch emulsions at different pH-levels

Anna Sundberg, Anders Strand, Lari Vähäsalo, Bjarne Holmbom

    Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

    33 Citeringar (Scopus)

    Sammanfattning

    The distribution of resin and fatty acids (RFAs) between the water phase and the lipophilic phase in colloidal pitch emulsions was determined as a function of pH. Model pitch emulsions were prepared and agitated at different pH, temperature, and NaCl concentration. After filtration, the concentration of dissolved RFAs in the water phase was determined. The experimental data were used for calculation of pKlw, that is, the pH at which 50% of the acids are dissolved in the water phase. At pH 3, all of the RFAs were associated with the colloidal droplets. The resin acids were dissolved at lower pH than the fatty acids. Among the resin acids, dehydroabietic acid had the lowest pKlw. The pKlw of fatty acids depended greatly on the chain length and degree of unsaturation. Fatty acids with more than 20 carbon atoms had a low water solubility even above pH 10. Increasing the NaCl concentration increased the pKlw. The kinetics of the phase distribution was very rapid.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)912–919
    Antal sidor8
    TidskriftJournal of Dispersion Science and Technology
    Volym30
    Utgåva6
    DOI
    StatusPublicerad - 2009
    MoE-publikationstypA1 Tidskriftsartikel-refererad

    Nyckelord

    • Dissolved substances
    • fatty acids
    • phase distribution
    • pitch
    • pKa
    • resin acids

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