Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al2O3 catalyst

Esa Toukoniitty; Päivi Mäki-Arvela; Johan Wärnå; Tapio Salmi

doi:10.1016/S0920-5861(00)00638-6

Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al₂O₃ catalyst

Esa Toukoniitty^*
, Päivi Mäki-Arvela
, Johan Wärnå
, Tapio Salmi

^*Korresponderande författare för detta arbete

Teknisk kemi och reaktionsteknik

Forskningsoutput: Tidskriftsbidrag › Konferensartikel › Vetenskaplig › Peer review

32 Citeringar (Scopus)

Sammanfattning

A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.

Originalspråk	Engelska
Sidor (från-till)	411-417
Antal sidor	7
Tidskrift	Catalysis Today
Volym	66
Nummer	2-4
DOI	https://doi.org/10.1016/S0920-5861(00)00638-6
Status	Publicerad - 30 mars 2001
MoE-publikationstyp	A4 Artikel i en konferenspublikation
Evenemang	Catalysis in Multiphase Reactors - Napoles, Italien Varaktighet: 29 maj 2000 → 29 maj 2000

Finansiering

The authors are grateful to Mr. Markku Reunanen for his contribution to the GC–MS analyses and to Mr. Kari Eränen for the construction of the hydrogenation equipment. The financial support received from the Academy of Finland and the Graduate School in Chemical Engineering is gratefully acknowledged.

Åtkomst av dokument

10.1016/S0920-5861(00)00638-6

Andra filer och länkar

Länk till publikationen i Scopus

Citera det här

@article{0aa5578956f24c20b6572faeca57344b,

title = "Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al2O3 catalyst",

abstract = "A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.",

keywords = "1-Phenyl-1,2-propanedione, Enantioselective hydrogenation, Pt/AlO catalyst",

author = "Esa Toukoniitty and P{\"a}ivi M{\"a}ki-Arvela and Johan W{\"a}rn{\aa} and Tapio Salmi",

note = "Funding Information: The authors are grateful to Mr. Markku Reunanen for his contribution to the GC–MS analyses and to Mr. Kari Er{\"a}nen for the construction of the hydrogenation equipment. The financial support received from the Academy of Finland and the Graduate School in Chemical Engineering is gratefully acknowledged. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.; Catalysis in Multiphase Reactors ; Conference date: 29-05-2000 Through 29-05-2000",

year = "2001",

month = mar,

day = "30",

doi = "10.1016/S0920-5861(00)00638-6",

language = "English",

volume = "66",

pages = "411--417",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier",

number = "2-4",

}

TY - JOUR

T1 - Modeling of the enantioselective hydrogenation of 1-phenyl-1,2-propanedione over Pt/Al2O3 catalyst

AU - Toukoniitty, Esa

AU - Mäki-Arvela, Päivi

AU - Wärnå, Johan

AU - Salmi, Tapio

N1 - Funding Information: The authors are grateful to Mr. Markku Reunanen for his contribution to the GC–MS analyses and to Mr. Kari Eränen for the construction of the hydrogenation equipment. The financial support received from the Academy of Finland and the Graduate School in Chemical Engineering is gratefully acknowledged. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.

PY - 2001/3/30

Y1 - 2001/3/30

N2 - A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.

AB - A kinetic model was developed for the enantioselective hydrogenation of 1-phenyl-1,2-propanedione based on parallel racemic and enantioselective routes in the presence of cinchonidine. The Langmuir-Hinshelwood type of competitive adsorption approach was used in the model, which was combined with a batch reactor model. The proposed model could sufficiently describe the observed kinetic results.

KW - 1-Phenyl-1,2-propanedione

KW - Enantioselective hydrogenation

KW - Pt/AlO catalyst

UR - https://www.scopus.com/pages/publications/0035970426

U2 - 10.1016/S0920-5861(00)00638-6

DO - 10.1016/S0920-5861(00)00638-6

M3 - Conference article

AN - SCOPUS:0035970426

SN - 0920-5861

VL - 66

SP - 411

EP - 417

JO - Catalysis Today

JF - Catalysis Today

IS - 2-4

T2 - Catalysis in Multiphase Reactors

Y2 - 29 May 2000 through 29 May 2000

ER -