Mechanisms of asymmetric heterogeneous catalysis

D. Yu Murzin*, P. Mäki-Arvela, T. Salmi

*Korresponderande författare för detta arbete

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

8 Citeringar (Scopus)

Sammanfattning

Asymmetric catalysis plays an important role in present-day production of pharmaceuticals. It can be predicted that enantioselective catalysis will dominate in the future, replacing conventional stoichiometric methods. Heterogeneous catalysts offer several advantages compared to their homogeneous counterparts. In the present review mechanisms of asymmetric heterogeneous catalysis are discussed and the different ways of chirality transfer are addressed. Enantioselection is possible over chiral supports and chiral metals exhibiting intrinsic chirality, as well as over modified metal supported catalysts. The interactions between a reactant and a modifier are very specific being critical for achieving high enantioselectivities.

OriginalspråkEngelska
Sidor (från-till)323-333
Antal sidor11
TidskriftKinetics and Catalysis
Volym44
Utgåva3
DOI
StatusPublicerad - maj 2003
MoE-publikationstypA1 Tidskriftsartikel-refererad

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