Liquid-phase hydrogenation of citral for production of citronellol: Catalyst selection

P. Mäki-Arvela, L. P. Tiainen, M. Lindblad, K. Demirkan, N. Kumar, R. Sjöholm, T. Ollonqvist, J. Väyrynen, T. Salmi, D. Yu Murzin*

*Korresponderande författare för detta arbete

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

66 Citeringar (Scopus)

Sammanfattning

Selective hydrogenation of citral to citronellol has been investigated over Ni supported catalysts. The aim was to compare different support materials and catalyst preparation methods. Selectivity to citronellol was dependent on conversion. The highest maximum selectivity towards citronellol for a Ni/Al2O3 (16.7wt.% Ni) catalyst at 2.3bar hydrogen increased from 70% in ethanol to 85% 2-pentanol, where acetalisation could be totally eliminated. In ethanol the highest maximum selectivities to citronellol were about 83% over a 8.8wt.% Ni/Al2O3 catalyst prepared by atomic layer epitaxy (ALE) method. The lower hydrogenation pressure (2.3bar) favoured the formation of citronellol compared to results obtained at 5.3bar hydrogen for all other catalysts, but not for Ni/Al2O3 (16.7wt.%). Both a bimetallic Ni-Cu/SiO2 (10wt.% Ni, 3wt.% Cu) catalyst and a Ni/SiO2 (17.6wt.% Ni) catalyst prepared by ALE method showed high selectivities to citronellol, 79 and 76%, respectively at 5.3bar hydrogen. An optimum hydrogenation rate and an optimum specific metal surface area in the catalyst gave the highest selectivities to the desired intermediate, citronellol. Ni supported Y zeolite catalysts were not selective towards formation of citronellol. Instead these catalysts favoured other reactions, like cyclisation, dehydrogenation and cracking.

OriginalspråkEngelska
Sidor (från-till)271-288
Antal sidor18
TidskriftApplied Catalysis A: General
Volym241
Utgåva1-2
DOI
StatusPublicerad - 20 feb 2003
MoE-publikationstypA1 Tidskriftsartikel-refererad

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