Sammanfattning
Lignan hydroxymatairesinol (HMR) extracted from Norway spruce knots was oxidized to the lignan oxomatairesinol (oxoMAT) in a semi-batch glass reactor under the atmospheric pressure in the presence of oxygen (5-49 vol.% in nitrogen) over 2 wt.% Au/Al2O3 catalyst, using propan-2-ol-water mixture as a solvent. The following kinetic parameters were determined: adsorption constants, rate constants, reaction order for reagents, and energy of activation. Through the parameter estimation the experimental data were fitted to the advanced kinetic model demonstrating a good correlation between the model and experiments.
Originalspråk | Odefinierat/okänt |
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Sidor (från-till) | 154–161 |
Tidskrift | Journal of Molecular Catalysis A: Chemical |
Volym | 388-389 |
Nummer | SI |
DOI | |
Status | Publicerad - 2014 |
MoE-publikationstyp | A1 Tidskriftsartikel-refererad |