Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

Dmitry Murzin; Sonia Garcia; Vincezo Russo; Teuvo Kilpiö; Lidia Godina; Anton Tokarev; Alexey V. Kirilin; Irina L. Simakova; Stephen Poulston; Dmitry A. Sladkovskiy; Johan Wärnå

doi:10.1021/acs.iecr.7b01636

Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

Dmitry Murzin, Sonia Garcia, Vincezo Russo, Teuvo Kilpiö, Lidia Godina, Anton Tokarev, Alexey V. Kirilin, Irina L. Simakova, Stephen Poulston, Dmitry A. Sladkovskiy, Johan Wärnå

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

27 Citeringar (Scopus)

Sammanfattning

The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO₂ but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	13240–13253
Tidskrift	Industrial & Engineering Chemistry Research
Volym	56
Nummer	45
DOI	https://doi.org/10.1021/acs.iecr.7b01636
Status	Publicerad - 2017
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Nyckelord

Chemical Engineering

Åtkomst av dokument

10.1021/acs.iecr.7b01636

http://pubs.acs.org/doi/abs/10.1021/acs.iecr.7b01636

Citera det här

Murzin, D., Garcia, S., Russo, V., Kilpiö, T., Godina, L., Tokarev, A., Kirilin, A. V., Simakova, I. L., Poulston, S., Sladkovskiy, D. A., & Wärnå, J. (2017). Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol. Industrial & Engineering Chemistry Research, 56(45), 13240–13253. https://doi.org/10.1021/acs.iecr.7b01636

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title = "Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol",

abstract = "The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.",

keywords = "Chemical Engineering, Chemical Engineering, Chemical Engineering",

author = "Dmitry Murzin and Sonia Garcia and Vincezo Russo and Teuvo Kilpi{\"o} and Lidia Godina and Anton Tokarev and Kirilin, {Alexey V.} and Simakova, {Irina L.} and Stephen Poulston and Sladkovskiy, {Dmitry A.} and Johan W{\"a}rn{\aa}",

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year = "2017",

doi = "10.1021/acs.iecr.7b01636",

language = "Odefinierat/ok{\"a}nt",

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journal = "Industrial & Engineering Chemistry Research",

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TY - JOUR

T1 - Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

AU - Murzin, Dmitry

AU - Garcia, Sonia

AU - Russo, Vincezo

AU - Kilpiö, Teuvo

AU - Godina, Lidia

AU - Tokarev, Anton

AU - Kirilin, Alexey V.

AU - Simakova, Irina L.

AU - Poulston, Stephen

AU - Sladkovskiy, Dmitry A.

AU - Wärnå, Johan

N1 - tk. This article is part of the Tapio Salmi Festschrift special issue.

PY - 2017

Y1 - 2017

N2 - The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

AB - The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

KW - Chemical Engineering

U2 - 10.1021/acs.iecr.7b01636

DO - 10.1021/acs.iecr.7b01636

M3 - Artikel

SN - 0888-5885

VL - 56

SP - 13240

EP - 13253

JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

IS - 45

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