Kinetic modeling using temperature as an on-line measurement: Application to the hydrolysis of acetic anhydride, a revisited kinetic model

Elizabeth Antonia Garcia-Hernandez, Camilla Ribeiro Souza, Lamiae Vernières-Hassimi, Sebastien Leveneur

    Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

    4 Citeringar (Scopus)

    Sammanfattning

    The use of calorimeter in chemical reaction engineering is a powerful tool to estimate kinetic constants. Indeed, reaction temperature is used as an online analytical signal. Nevertheless, the thermal characterization of the calorimeter must be done to avoid wrong estimation. The hydrolysis of acetic anhydride was used as a reaction model in a handmade calorimeter, because it is a fast and exothermic reaction. Several research groups have studied this reaction without taking into account the autocatalytic effect due to the production of acetic acid. To fill this gap, a kinetic model was developed by taking this phenomenon and in a thermally characterized handmade calorimeter. The estimated kinetic constants in the handmade calorimeter were found to be similar than in the established calorimeter Mettler Toledo RC1.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)
    Antal sidor10
    TidskriftThermochimica Acta
    Volym682
    DOI
    StatusPublicerad - 2019
    MoE-publikationstypA1 Tidskriftsartikel-refererad

    Nyckelord

    • Exothermic reaction
    • Isoperibolic mode
    • calorimeter

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