Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

Alexey Kirilin; Johan Wärnå; Anton Tokarev; Dmitry Murzin

doi:10.1021/ie403813y

Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

Alexey Kirilin, Johan Wärnå, Anton Tokarev, Dmitry Murzin

Teknisk kemi och reaktionsteknik

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

30 Citeringar (Scopus)

Sammanfattning

Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C₆-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al₂O₃ catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	4580–4588
Tidskrift	Industrial & Engineering Chemistry Research
Volym	53
Nummer	12
DOI	https://doi.org/10.1021/ie403813y
Status	Publicerad - 2014
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Åtkomst av dokument

10.1021/ie403813y

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title = "Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3",

abstract = "Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.",

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year = "2014",

doi = "10.1021/ie403813y",

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AU - Murzin, Dmitry

PY - 2014

Y1 - 2014

N2 - Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

AB - Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

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DO - 10.1021/ie403813y

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JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

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