Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation

Aleksandrina Sulman; Päivi Mäki-Arvela; Louis Bomont; Moldir Alda-Onggar; Vyacheslav Fedorov; Vincenzo Russo; Kari Eränen; Markus Peurla; Uliana Akhmetzyanova; Lenka Skuhrovcová; Zdeněk Tišler; Henrik Grénman; Johan Wärnå; Dmitry Murzin

doi:10.1007/s10562-019-02856-x

Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation

Aleksandrina Sulman, Päivi Mäki-Arvela, Louis Bomont, Moldir Alda-Onggar, Vyacheslav Fedorov, Vincenzo Russo, Kari Eränen, Markus Peurla, Uliana Akhmetzyanova, Lenka Skuhrovcová, Zdeněk Tišler, Henrik Grénman, Johan Wärnå, Dmitry Murzin

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

30 Citeringar (Scopus)

Sammanfattning

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	2453–2467
Tidskrift	Catalysis Letters
Volym	149
Nummer	9
DOI	https://doi.org/10.1007/s10562-019-02856-x
Status	Publicerad - 2019
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Åtkomst av dokument

10.1007/s10562-019-02856-x

https://link.springer.com/article/10.1007/s10562-019-02856-x

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title = "Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation",

abstract = "Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.",

author = "Aleksandrina Sulman and P{\"a}ivi M{\"a}ki-Arvela and Louis Bomont and Moldir Alda-Onggar and Vyacheslav Fedorov and Vincenzo Russo and Kari Er{\"a}nen and Markus Peurla and Uliana Akhmetzyanova and Lenka Skuhrovcov{\'a} and Zden{\v e}k Ti{\v s}ler and Henrik Gr{\'e}nman and Johan W{\"a}rn{\aa} and Dmitry Murzin",

note = "tk. Vyacheslav Fedorov is also affiliated with {\AA}AU",

year = "2019",

doi = "10.1007/s10562-019-02856-x",

language = "Odefinierat/ok{\"a}nt",

volume = "149",

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journal = "Catalysis Letters",

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TY - JOUR

T1 - Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation

AU - Sulman, Aleksandrina

AU - Mäki-Arvela, Päivi

AU - Bomont, Louis

AU - Alda-Onggar, Moldir

AU - Fedorov, Vyacheslav

AU - Russo, Vincenzo

AU - Eränen, Kari

AU - Peurla, Markus

AU - Akhmetzyanova, Uliana

AU - Skuhrovcová, Lenka

AU - Tišler, Zdeněk

AU - Grénman, Henrik

AU - Wärnå, Johan

AU - Murzin, Dmitry

N1 - tk. Vyacheslav Fedorov is also affiliated with ÅAU

PY - 2019

Y1 - 2019

N2 - Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.

AB - Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.

U2 - 10.1007/s10562-019-02856-x

DO - 10.1007/s10562-019-02856-x

M3 - Artikel

SN - 1011-372X

VL - 149

SP - 2453

EP - 2467

JO - Catalysis Letters

JF - Catalysis Letters

IS - 9

ER -