Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?

Shashi Kant Shukla, Dariush Nikjoo, Jyri-Pekka Mikkola

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

2 Citeringar (Scopus)

Sammanfattning

A critical analysis of the role of Hammett basicity (H−) and aqueous basicity (pKa) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H− nor pKa correlates with the CO2 w/w% capacity in the studied DESs. Instead, strong “synergistic interactions” between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.
OriginalspråkEngelska
Sidor (från-till)966-970
Antal sidor5
TidskriftPhysical Chemistry Chemical Physics
Volym22
DOI
StatusPublicerad - 2020
MoE-publikationstypA1 Tidskriftsartikel-refererad

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