Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

Kevin Bourhis; Jonathan Massera; Laeticia Petit; Heikki Ihalainen; Alexandre Fargues; Thierry Cardinal; Leena Hupa; Mikko Hupa; Marc Dussauze; Vincent Rodriguez; Catherine Boussard-Plédel; Bruno Bureau; Claire Roiland; Monica Ferraris

doi:10.1016/j.materresbull.2014.11.0480

Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

Kevin Bourhis, Jonathan Massera, Laeticia Petit, Heikki Ihalainen, Alexandre Fargues, Thierry Cardinal, Leena Hupa, Mikko Hupa, Marc Dussauze, Vincent Rodriguez, Catherine Boussard-Plédel, Bruno Bureau, Claire Roiland, Monica Ferraris

Molekylärvetenskap och -teknik

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

Sammanfattning

The effect of P₂O₅ and/or Al₂O₃ addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P₂O₅ and/or Al₂O₃, which were probed by FTIR, ¹¹B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the ^[3]B/^[4]B ratio are explained by a charge compensation mechanism due to the formation of AlO₄, PO₄ groups and the formation of AlOP linkages in the glass network. From the absorption and luminescence properties of the Er³⁺ ions at 980 nm and 1530 nm, declustering is suspected for the highest P₂O₅ concentrations while for the highest Al₂O₃ concentrations no declustering is observed.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	41–50
Tidskrift	Materials Research Bulletin
Volym	63
DOI	https://doi.org/10.1016/j.materresbull.2014.11.0480
Status	Publicerad - 2015
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Åtkomst av dokument

10.1016/j.materresbull.2014.11.0480

Citera det här

Bourhis, K., Massera, J., Petit, L., Ihalainen, H., Fargues, A., Cardinal, T., Hupa, L., Hupa, M., Dussauze, M., Rodriguez, V., Boussard-Plédel, C., Bureau, B., Roiland, C., & Ferraris, M. (2015). Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties. Materials Research Bulletin, 63, 41–50. https://doi.org/10.1016/j.materresbull.2014.11.0480

@article{ff52e196d68042e7880f1f9f0b9c81e2,

title = "Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties",

abstract = "The effect of P2O5 and/or Al2O3 addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P2O5 and/or Al2O3, which were probed by FTIR, 11B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the [3]B/[4]B ratio are explained by a charge compensation mechanism due to the formation of AlO4, PO4 groups and the formation of AlOP linkages in the glass network. From the absorption and luminescence properties of the Er3+ ions at 980 nm and 1530 nm, declustering is suspected for the highest P2O5 concentrations while for the highest Al2O3 concentrations no declustering is observed.",

author = "Kevin Bourhis and Jonathan Massera and Laeticia Petit and Heikki Ihalainen and Alexandre Fargues and Thierry Cardinal and Leena Hupa and Mikko Hupa and Marc Dussauze and Vincent Rodriguez and Catherine Boussard-Pl{\'e}del and Bruno Bureau and Claire Roiland and Monica Ferraris",

note = "ook WOS: Influence of P2O5 and Al2O3 content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties",

year = "2015",

doi = "10.1016/j.materresbull.2014.11.0480",

language = "Odefinierat/ok{\"a}nt",

volume = "63",

pages = "41–50",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier",

}

Bourhis, K, Massera, J, Petit, L, Ihalainen, H, Fargues, A, Cardinal, T, Hupa, L , Hupa, M, Dussauze, M, Rodriguez, V, Boussard-Plédel, C, Bureau, B, Roiland, C & Ferraris, M 2015, 'Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties', Materials Research Bulletin, vol. 63, s. 41–50. https://doi.org/10.1016/j.materresbull.2014.11.0480

TY - JOUR

T1 - Influence of P₂O₅ and Al₂O₃ content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

AU - Bourhis, Kevin

AU - Massera, Jonathan

AU - Petit, Laeticia

AU - Ihalainen, Heikki

AU - Fargues, Alexandre

AU - Cardinal, Thierry

AU - Hupa, Leena

AU - Hupa, Mikko

AU - Dussauze, Marc

AU - Rodriguez, Vincent

AU - Boussard-Plédel, Catherine

AU - Bureau, Bruno

AU - Roiland, Claire

AU - Ferraris, Monica

N1 - ook WOS: Influence of P2O5 and Al2O3 content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

PY - 2015

Y1 - 2015

N2 - The effect of P2O5 and/or Al2O3 addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P2O5 and/or Al2O3, which were probed by FTIR, 11B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the [3]B/[4]B ratio are explained by a charge compensation mechanism due to the formation of AlO4, PO4 groups and the formation of AlOP linkages in the glass network. From the absorption and luminescence properties of the Er3+ ions at 980 nm and 1530 nm, declustering is suspected for the highest P2O5 concentrations while for the highest Al2O3 concentrations no declustering is observed.

AB - The effect of P2O5 and/or Al2O3 addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P2O5 and/or Al2O3, which were probed by FTIR, 11B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the [3]B/[4]B ratio are explained by a charge compensation mechanism due to the formation of AlO4, PO4 groups and the formation of AlOP linkages in the glass network. From the absorption and luminescence properties of the Er3+ ions at 980 nm and 1530 nm, declustering is suspected for the highest P2O5 concentrations while for the highest Al2O3 concentrations no declustering is observed.

U2 - 10.1016/j.materresbull.2014.11.0480

DO - 10.1016/j.materresbull.2014.11.0480

M3 - Artikel

SN - 0025-5408

VL - 63

SP - 41

EP - 50

JO - Materials Research Bulletin

JF - Materials Research Bulletin

ER -