Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

Reko Leino; Luttikhedde HJG; L Langstedt; A Penninkangas

Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

Reko Leino, Luttikhedde HJG, L Langstedt, A Penninkangas

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Sammanfattning

The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

Originalspråk	Odefinierat/okänt
Sidor (från-till)	4149–4151
Antal sidor	3
Tidskrift	Tetrahedron Letters
Volym	43
Nummer	23
Status	Publicerad - 2002
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

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title = "Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes",

abstract = "The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.",

author = "Reko Leino and Luttikhedde HJG and L Langstedt and A Penninkangas",

year = "2002",

language = "Odefinierat/ok{\"a}nt",

volume = "43",

pages = "4149–4151",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "23",

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TY - JOUR

T1 - Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

AU - Leino, Reko

AU - HJG, Luttikhedde

AU - Langstedt, L

AU - Penninkangas, A

PY - 2002

Y1 - 2002

N2 - The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

M3 - Artikel

SN - 0040-4039

VL - 43

SP - 4149

EP - 4151

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -