TY - JOUR
T1 - Hemicelluloses from stone pine, holm oak, and Norway spruce with subcritical water extraction − comparative study with characterization and kinetics
AU - Andérez, Maria
AU - Rissanen, Jussi
AU - Pérez Nebreda, Andrea
AU - Xu, Chunlin
AU - Willför, Stefan
AU - García Serna, Juan
AU - Salmi, Tapio
AU - Grénman, Henrik
N1 - tk.
3pk
PY - 2018
Y1 - 2018
N2 - Extraction of hemicelluloses with subcritical water is an efficient and environmentally benign way of fractionating biomass, including lignocelluloses. The composition and extraction behavior of hemicelluloses from wood depends significantly on the species, which affects the obtained product and the requirements of the extraction process. The current work focuses on the extraction of hemicelluloses from three chemically and structurally different, interesting and economically important tree species namely stone pine (Pinus pinea), holm oak (Quercus ilex), and Norway spruce (Picea abies), for which the literature on holm oak and stone pine hemicelluloses is almost non-existent. The work was performed with identical experimental methods, to obtain completely comparable results. The effect of temperature, raw material and solid-liquid ratio on the extraction kinetics, pH and molar mass, was studied. The results revealed significant differences in the extraction behavior and composition of the different species.
AB - Extraction of hemicelluloses with subcritical water is an efficient and environmentally benign way of fractionating biomass, including lignocelluloses. The composition and extraction behavior of hemicelluloses from wood depends significantly on the species, which affects the obtained product and the requirements of the extraction process. The current work focuses on the extraction of hemicelluloses from three chemically and structurally different, interesting and economically important tree species namely stone pine (Pinus pinea), holm oak (Quercus ilex), and Norway spruce (Picea abies), for which the literature on holm oak and stone pine hemicelluloses is almost non-existent. The work was performed with identical experimental methods, to obtain completely comparable results. The effect of temperature, raw material and solid-liquid ratio on the extraction kinetics, pH and molar mass, was studied. The results revealed significant differences in the extraction behavior and composition of the different species.
KW - Chemical Engineering
KW - Chemical Engineering
KW - Chemical Engineering
U2 - 10.1016/j.supflu.2017.07.001
DO - 10.1016/j.supflu.2017.07.001
M3 - Artikel
SN - 0896-8446
VL - 133
SP - 647
EP - 657
JO - Journal of Supercritical Fluids
JF - Journal of Supercritical Fluids
IS - Part 2
ER -