Gold catalysts for selective aerobic oxidation of the lignan hydroxymatairesinol to oxomatairesinol: Catalyst deactivation and regeneration

Olga A. Simakova; Elena V. Murzina; Anne-Riikka Leino; Päivi Mäki-Arvela; Stefan Willför; Dmitry Yu Murzin

doi:10.1007/s10562-012-0855-8

Gold catalysts for selective aerobic oxidation of the lignan hydroxymatairesinol to oxomatairesinol: Catalyst deactivation and regeneration

Olga A. Simakova
, Elena V. Murzina
, Anne-Riikka Leino
, Päivi Mäki-Arvela
, Stefan Willför
, Dmitry Yu Murzin^*

^*Korresponderande författare för detta arbete

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

7 Citeringar (Scopus)

Sammanfattning

The lignan oxomatairesinol was synthesized from the biomass-derived lignan hydroxymatairesinol via selective aerobic oxidation over a heterogeneous gold catalyst. The catalyst was prepared by direct ion-exchange and characterized by XRD, TEM and ICP-OES methods. The reaction was carried out at 70 °C and atmospheric pressure in a semi-batch reactor. To reveal the origin of catalyst deactivation, spent catalysts were studied by TEM, XRD, nitrogen physisorption, ICP-OES, TPO, and DSCTGA techniques. Several regeneration procedures were applied-extraction by several solvents and calcinations in the oxidizing atmosphere. The former one was found to be the most effective way for the catalyst regeneration.

Originalspråk	Engelska
Sidor (från-till)	1011-1019
Antal sidor	9
Tidskrift	Catalysis Letters
Volym	142
DOI	https://doi.org/10.1007/s10562-012-0855-8
Status	Publicerad - 2012
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Åtkomst av dokument

10.1007/s10562-012-0855-8Licens: Publisher rights policy

Andra filer och länkar

Länk till publikationen i Scopus

Citera det här

@article{84a33e53ebd340d28df491d9ecaff6d8,

title = "Gold catalysts for selective aerobic oxidation of the lignan hydroxymatairesinol to oxomatairesinol: Catalyst deactivation and regeneration",

abstract = "The lignan oxomatairesinol was synthesized from the biomass-derived lignan hydroxymatairesinol via selective aerobic oxidation over a heterogeneous gold catalyst. The catalyst was prepared by direct ion-exchange and characterized by XRD, TEM and ICP-OES methods. The reaction was carried out at 70 °C and atmospheric pressure in a semi-batch reactor. To reveal the origin of catalyst deactivation, spent catalysts were studied by TEM, XRD, nitrogen physisorption, ICP-OES, TPO, and DSCTGA techniques. Several regeneration procedures were applied-extraction by several solvents and calcinations in the oxidizing atmosphere. The former one was found to be the most effective way for the catalyst regeneration.",

keywords = "Biomass, Catalyst deactivation, Gold catalysts, Hydroxymatairesinol, Lignans, Oxomatairesinol, Selective oxidation",

author = "Simakova, \{Olga A.\} and Murzina, \{Elena V.\} and Anne-Riikka Leino and P{\"a}ivi M{\"a}ki-Arvela and Stefan Willf{\"o}r and Murzin, \{Dmitry Yu\}",

year = "2012",

doi = "10.1007/s10562-012-0855-8",

language = "English",

volume = "142",

pages = "1011--1019",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer",

}

TY - JOUR

T1 - Gold catalysts for selective aerobic oxidation of the lignan hydroxymatairesinol to oxomatairesinol

T2 - Catalyst deactivation and regeneration

AU - Simakova, Olga A.

AU - Murzina, Elena V.

AU - Leino, Anne-Riikka

AU - Mäki-Arvela, Päivi

AU - Willför, Stefan

AU - Murzin, Dmitry Yu

PY - 2012

Y1 - 2012

N2 - The lignan oxomatairesinol was synthesized from the biomass-derived lignan hydroxymatairesinol via selective aerobic oxidation over a heterogeneous gold catalyst. The catalyst was prepared by direct ion-exchange and characterized by XRD, TEM and ICP-OES methods. The reaction was carried out at 70 °C and atmospheric pressure in a semi-batch reactor. To reveal the origin of catalyst deactivation, spent catalysts were studied by TEM, XRD, nitrogen physisorption, ICP-OES, TPO, and DSCTGA techniques. Several regeneration procedures were applied-extraction by several solvents and calcinations in the oxidizing atmosphere. The former one was found to be the most effective way for the catalyst regeneration.

AB - The lignan oxomatairesinol was synthesized from the biomass-derived lignan hydroxymatairesinol via selective aerobic oxidation over a heterogeneous gold catalyst. The catalyst was prepared by direct ion-exchange and characterized by XRD, TEM and ICP-OES methods. The reaction was carried out at 70 °C and atmospheric pressure in a semi-batch reactor. To reveal the origin of catalyst deactivation, spent catalysts were studied by TEM, XRD, nitrogen physisorption, ICP-OES, TPO, and DSCTGA techniques. Several regeneration procedures were applied-extraction by several solvents and calcinations in the oxidizing atmosphere. The former one was found to be the most effective way for the catalyst regeneration.

KW - Biomass

KW - Catalyst deactivation

KW - Gold catalysts

KW - Hydroxymatairesinol

KW - Lignans

KW - Oxomatairesinol

KW - Selective oxidation

UR - https://www.scopus.com/pages/publications/84865409798

U2 - 10.1007/s10562-012-0855-8

DO - 10.1007/s10562-012-0855-8

M3 - Article

AN - SCOPUS:84865409798

SN - 1011-372X

VL - 142

SP - 1011

EP - 1019

JO - Catalysis Letters

JF - Catalysis Letters

ER -

Gold catalysts for selective aerobic oxidation of the lignan hydroxymatairesinol to oxomatairesinol: Catalyst deactivation and regeneration

Sammanfattning

Åtkomst av dokument

Andra filer och länkar

Fingeravtryck

Citera det här