Direct hydrodeoxygenation of algal lipids extracted from Chlorella alga

Hoang SH Nguyen, Päivi Mäki-Arvela, Uliana Akhmetzyanova, Zdeněk Tišler, Imane Hachemi, Andre Rudnäs, Annika Smeds, Kari Eränen, Atte Aho, Narendra Kumar, Jarl Hemming, Markus Peurla, Dmitry Murzin

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

13 Citeringar (Scopus)

Sammanfattning

BACKGROUNDHydrodeoxygenation (HDO) of Chlorella algal oil extracted with supercritical hexane and stearic acid as a model compound was investigated over several supported Ni and Mo2N–MoO2 catalysts in a semibatch reactor at 300 °C under 30 bar in the presence of hydrogen.RESULTSThe results showed that all catalysts were very active in HDO of stearic acid. With crude algal oil, a maximum conversion of lipids of 35% was found with an acidic Ni-HY-80 zeolite catalyst after 360 min. The main products in algal oil HDO were fatty acids; whereas maximally only 7% hydrocarbons were formed with Ni-HY-80. The main hydrocarbon products were formed via decarbonylation, as the hydrogenation/dehydration route was suppressed.CONCLUSIONSHydrodeoxygenation of crude Chlorella algal oil was demonstrated over nickel supported on beta zeolite and with a molybdenum oxide–nitride catalyst. Strong catalyst deactivation occurred for the former catalyst, whereas the latter retained its activity.
OriginalspråkOdefinierat/okänt
Sidor (från-till)741–748
TidskriftJournal of Chemical Technology and Biotechnology
Volym92
Utgåva4
DOI
StatusPublicerad - 2017
MoE-publikationstypA1 Tidskriftsartikel-refererad

Nyckelord

  • Chemical Engineering

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