Determination of the protonation constants of electrochemically polymerized poly(aniline) and poly(o-methylaniline)

Tom Lindfors*, Leo Harju

*Korresponderande författare för detta arbete

    Forskningsoutput: KonferensbidragPosterVetenskaplig

    Sammanfattning

    A method was developed for the determination of the protonation constants (K), the stoichiometric factor of the protonation reaction (n) and pH of the half-colour transition point (pH1/2) of three different types of electrochemically polymerized poly(aniline) (PANI) and poly(o-methylaniline) (PoMeANI) films. The protonation constants describe the reversible emeraldine base (EB) to emeraldine salt (ES) transition. The calculations of the constants were based on absorbance data obtained from UV-vis measurements of the polymer films equilibrated in pH buffer solutions between pH 2-12.
    OriginalspråkEngelska
    StatusPublicerad - 2008
    MoE-publikationstypO2 Other
    EvenemangICSM 2018, International Conference on Science and Technology of Synthetic Metals - Porto de Galinhas , Brasilien
    Varaktighet: 6 juli 200811 juli 2008

    Konferens

    KonferensICSM 2018, International Conference on Science and Technology of Synthetic Metals
    Land/TerritoriumBrasilien
    OrtPorto de Galinhas
    Period06/07/0811/07/08

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