Sammanfattning
A method was developed for the determination of the protonation constants (K), the stoichiometric factor of the protonation reaction (n) and pH of the half-colour transition point (pH1/2) of three different types of electrochemically polymerized poly(aniline) (PANI) and poly(o-methylaniline) (PoMeANI) films. The protonation constants describe the reversible emeraldine base (EB) to emeraldine salt (ES) transition. The calculations of the constants were based on absorbance data obtained from UV-vis measurements of the polymer films equilibrated in pH buffer solutions between pH 2-12.
Originalspråk | Engelska |
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Status | Publicerad - 2008 |
MoE-publikationstyp | O2 Other |
Evenemang | ICSM 2018, International Conference on Science and Technology of Synthetic Metals - Porto de Galinhas , Brasilien Varaktighet: 6 juli 2008 → 11 juli 2008 |
Konferens
Konferens | ICSM 2018, International Conference on Science and Technology of Synthetic Metals |
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Land/Territorium | Brasilien |
Ort | Porto de Galinhas |
Period | 06/07/08 → 11/07/08 |