Deoxygenation of palmitic and stearic acid over supported Pd catalysts: Effect of metal dispersion

Irina Simakova, Olga Simakova, Päivi Mäki-Arvela, Andrey Simakov, Miguel Estrada, Dmitry Yu Murzin*

*Korresponderande författare för detta arbete

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

185 Citeringar (Scopus)

Sammanfattning

Catalytic deoxygenation of palmitic and stearic acids mixture was studied over four synthesized Pd catalysts supported on synthetic carbon (Sibunit) in a semibatch reactor and dodecane as a solvent at 260-300 °C. The catalysts were prepared by precipitation deposition method using Pd chlorides as metal precursors. All catalysts contained 1 wt.% Pd, however, the metal dispersion was systematically varied. An optimum metal dispersion giving the highest reaction rate was observed. The main liquid phase products were n-heptadecane and n-pentadecane, which were formed in parallel. In addition to the particle size effect the impact of mass transfer was elucidated and a detail discussion on temperature programmed desorption of CO from the fresh and spent samples was provided.

OriginalspråkEngelska
Sidor (från-till)100-108
Antal sidor9
TidskriftApplied Catalysis A: General
Volym355
Utgåva1-2
DOI
StatusPublicerad - 28 feb 2009
MoE-publikationstypA1 Tidskriftsartikel-refererad

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