Cu-I-mediated degradation of polysaccharides leads to fragments with narrow polydispersities

Jani Rahkila, Filip S. Ekholm, Reko Leino

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

3 Citeringar (Scopus)
2 Nedladdningar (Pure)

Sammanfattning

Biomass derived oligo- and polysaccharides are important compounds for various applications, including biomedicine and material science. Their use, however, is often limited by inherent structural inhomogeneity of the starting materials. Here, a method for depolymerization of naturally occurring polysaccharides, including dextran, starch, xylan and galactoglucomannan, into well-defined fragments of narrow polydispersities is described, based on the use of in situ generated Cu-I species under the commonly employed CuAAC reaction conditions. The main strength of the reported method is its high versatility, both in terms of substrate scope and operational simplicity.
OriginalspråkOdefinierat/okänt
Sidor (från-till)1449–1454
Antal sidor6
TidskriftEuropean Journal of Organic Chemistry
Volym2018
Utgåva12
DOI
StatusPublicerad - 2018
MoE-publikationstypA1 Tidskriftsartikel-refererad

Nyckelord

  • Controlled depolymerization
  • Renewable resources

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