Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells

G. Dennler; A. J. Mozer; G. Juška; A. Pivrikas; R. Österbacka; A. Fuchsbauer; N. S. Sariciftci

doi:10.1016/j.orgel.2006.02.004

Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells

G. Dennler^*
, A. J. Mozer
, G. Juška
, A. Pivrikas
, R. Österbacka
, A. Fuchsbauer
, N. S. Sariciftci

^*Korresponderande författare för detta arbete

Fysik

Forskningsoutput: Tidskriftsbidrag › Artikel › Vetenskaplig › Peer review

169 Citeringar (Scopus)

Sammanfattning

Charge carrier mobility (μ), recombination kinetics, and lifetime (τ) have been investigated with the photo-induced charge carrier extraction by linearly increasing voltage technique (photo-CELIV) in blends of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C₆₁(PCBM). Different MDMO-PPV/PCBM ratios have been studied showing that increasing the PCBM content induces an increase of the photo-CELIV mobility up to two orders of magnitude. Simultaneously, the lifetime of the charge carriers decreases in such a way that the product μ × τ appears almost constant independently of the blend composition. Recombination kinetics close to the Langevin one is observed for all PCBM concentrations studied.

Originalspråk	Engelska
Sidor (från-till)	229-234
Antal sidor	6
Tidskrift	Organic Electronics
Volym	7
Nummer	4
DOI	https://doi.org/10.1016/j.orgel.2006.02.004
Status	Publicerad - aug. 2006
MoE-publikationstyp	A1 Tidskriftsartikel-refererad

Finansiering

The authors gratefully acknowledge the financial support of the Austrian Foundation for the Advancement of Science (FWF NANORAC Contract No: FWF-N00103000). They thank H. Neugebauer and C. Lungenschmied for fruitful discussions.

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title = "Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells",

abstract = "Charge carrier mobility (μ), recombination kinetics, and lifetime (τ) have been investigated with the photo-induced charge carrier extraction by linearly increasing voltage technique (photo-CELIV) in blends of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C61(PCBM). Different MDMO-PPV/PCBM ratios have been studied showing that increasing the PCBM content induces an increase of the photo-CELIV mobility up to two orders of magnitude. Simultaneously, the lifetime of the charge carriers decreases in such a way that the product μ × τ appears almost constant independently of the blend composition. Recombination kinetics close to the Langevin one is observed for all PCBM concentrations studied.",

keywords = "Bulk-heterojunction, Conjugated polymer, Fullerene, Lifetime, Mobility, Organic solar cells, Recombination kinetics",

author = "G. Dennler and Mozer, \{A. J.\} and G. Ju{\v s}ka and A. Pivrikas and R. {\"O}sterbacka and A. Fuchsbauer and Sariciftci, \{N. S.\}",

note = "Funding Information: The authors gratefully acknowledge the financial support of the Austrian Foundation for the Advancement of Science (FWF NANORAC Contract No: FWF-N00103000). They thank H. Neugebauer and C. Lungenschmied for fruitful discussions. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2006",

month = aug,

doi = "10.1016/j.orgel.2006.02.004",

language = "English",

volume = "7",

pages = "229--234",

journal = "Organic Electronics",

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T1 - Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells

AU - Dennler, G.

AU - Mozer, A. J.

AU - Juška, G.

AU - Pivrikas, A.

AU - Österbacka, R.

AU - Fuchsbauer, A.

AU - Sariciftci, N. S.

N1 - Funding Information: The authors gratefully acknowledge the financial support of the Austrian Foundation for the Advancement of Science (FWF NANORAC Contract No: FWF-N00103000). They thank H. Neugebauer and C. Lungenschmied for fruitful discussions. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2006/8

Y1 - 2006/8

N2 - Charge carrier mobility (μ), recombination kinetics, and lifetime (τ) have been investigated with the photo-induced charge carrier extraction by linearly increasing voltage technique (photo-CELIV) in blends of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C61(PCBM). Different MDMO-PPV/PCBM ratios have been studied showing that increasing the PCBM content induces an increase of the photo-CELIV mobility up to two orders of magnitude. Simultaneously, the lifetime of the charge carriers decreases in such a way that the product μ × τ appears almost constant independently of the blend composition. Recombination kinetics close to the Langevin one is observed for all PCBM concentrations studied.

AB - Charge carrier mobility (μ), recombination kinetics, and lifetime (τ) have been investigated with the photo-induced charge carrier extraction by linearly increasing voltage technique (photo-CELIV) in blends of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C61(PCBM). Different MDMO-PPV/PCBM ratios have been studied showing that increasing the PCBM content induces an increase of the photo-CELIV mobility up to two orders of magnitude. Simultaneously, the lifetime of the charge carriers decreases in such a way that the product μ × τ appears almost constant independently of the blend composition. Recombination kinetics close to the Langevin one is observed for all PCBM concentrations studied.

KW - Bulk-heterojunction

KW - Conjugated polymer

KW - Fullerene

KW - Lifetime

KW - Mobility

KW - Organic solar cells

KW - Recombination kinetics

UR - https://www.scopus.com/pages/publications/33747515686

U2 - 10.1016/j.orgel.2006.02.004

DO - 10.1016/j.orgel.2006.02.004

M3 - Article

AN - SCOPUS:33747515686

SN - 1566-1199

VL - 7

SP - 229

EP - 234

JO - Organic Electronics

JF - Organic Electronics

IS - 4

ER -

Charge carrier mobility and lifetime versus composition of conjugated polymer/fullerene bulk-heterojunction solar cells

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