Sammanfattning
The synthesis and characterization of 1- and 2-triisopropylsiloxy substituted bis(indenyl) zirconocenes is reported. The molecular structures of rac-[ethylenebis(2-(triisopropylsiloxy)-1-indenyl)]zirconium dichloride (6) and rac-[ethylenebis(2-(triisopropylsiloxy)-4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride (8) have been determined and reveal that complex (6) crystallizes in the indenyl-forward (II) conformation while (8) adopts the indenyl-backward (Y) conformation. (C) 1998 Elsevier Science S.A. All rights reserved.
| Originalspråk | Odefinierat/okänt |
|---|---|
| Sidor (från-till) | 127–134 |
| Antal sidor | 8 |
| Tidskrift | Journal of Organometallic Chemistry |
| Volym | 555 |
| Nummer | 1 |
| Status | Publicerad - 1998 |
| MoE-publikationstyp | A1 Tidskriftsartikel-refererad |
Nyckelord
- ansa-zirconocene
- indenyl
- triisopropylsiloxy