Bis(triisopropylsiloxyindenyl)zirconocenes

Luttikhedde HJG, Reko Leino, A Lehtonen, JH Nasman

    Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

    25 Citeringar (Scopus)

    Sammanfattning

    The synthesis and characterization of 1- and 2-triisopropylsiloxy substituted bis(indenyl) zirconocenes is reported. The molecular structures of rac-[ethylenebis(2-(triisopropylsiloxy)-1-indenyl)]zirconium dichloride (6) and rac-[ethylenebis(2-(triisopropylsiloxy)-4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride (8) have been determined and reveal that complex (6) crystallizes in the indenyl-forward (II) conformation while (8) adopts the indenyl-backward (Y) conformation. (C) 1998 Elsevier Science S.A. All rights reserved.
    OriginalspråkOdefinierat/okänt
    Sidor (från-till)127–134
    Antal sidor8
    TidskriftJournal of Organometallic Chemistry
    Volym555
    Utgåva1
    StatusPublicerad - 1998
    MoE-publikationstypA1 Tidskriftsartikel-refererad

    Nyckelord

    • ansa-zirconocene
    • indenyl
    • triisopropylsiloxy

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