Acylation of (R,S)-1-phenylethanol with ethyl acetate over an immobilized enzyme

Päivi Mäki-Arvela*, Serap Sahin, Kari Eränen, Dmitry Yu Murzin

*Korresponderande författare för detta arbete

Forskningsoutput: TidskriftsbidragArtikelVetenskapligPeer review

2 Citeringar (Scopus)

Sammanfattning

Acylation of (R,S)-1-phenylethanol, which is a product of acetophenone hydrogenation, over a Pd-supported catalyst, was studied in ethyl acetate with an immobilized lipase. It was demonstrated that in the presence of hydrogen and Pd/C in the reaction medium the (R,S)-1-phenylethanol acylation rate is not hindered, whereas the selectivity was strongly altered in the latter case, leading to significant amounts of side products.

OriginalspråkEngelska
Sidor (från-till)245-252
Antal sidor8
TidskriftResearch on Chemical Intermediates
Volym36
Utgåva3
DOI
StatusPublicerad - apr 2010
MoE-publikationstypA1 Tidskriftsartikel-refererad

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